A novel wide bandgap conjugated polymer (2.0 eV) based on bithiazole for high efficiency polymer solar cells
文献类型：期刊论文
| 作者 | Guo, Bing1; Li, Wanbin1; Guo, Xia1; Meng, Xiangyi2; Ma, Wei2; Zhang, Maojie1; Li, Yongfang1,3 |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2017-04-01 |
| 卷号 | 34页码:556-561 |
| 关键词 | Wide Bandgap Conjugated Polymer Bithiazole Polymer Solar Cells |
| 英文摘要 | An efficient wide bandgap conjugated polymer (PTZ6) based on alkoxylphenyl substituted benzodithiophene as donor unit and bithiazole as acceptor unit was developed for polymer solar cells (PSCs). The polymer exhibited a wide bandgap of 2.0 eV with strong absorption in the range of 300-620 nm, and a low-lying highest occupied molecular orbital (HOMO) energy level of -5.36 eV. The PSCs based on PTZ6: PC71BM show a PCE of 8.1% with a V-oc of 0.96 V, a J(sc) of 10.9 mA cm(-2) and a high FF of 76.7%, which is among the highest values for the fullerene PSCs based on conjugated polymer donors with bandgap near to 2.0 eV. Moreover, for this blend system, the photovoltaic performance of the devices changes little when the active layer thickness increases from 90 nm to 220 nm. More importantly, the non-fullerene PSCs based on PTZ6: ITIC exhibit a PCE of 10.3% with a high V-oc of 1.01 V, which should be the best value for the non-fullerene PSCs with the Eloss less than 0.6 eV to date. Our results indicate that PTZ6 is a promising wide bandgap polymer donor for the photovoltaic application in PSCs. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39032]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Lab Adv Optoelect Mat, Suzhou 215123, Peoples R China 2.Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Bing,Li, Wanbin,Guo, Xia,et al. A novel wide bandgap conjugated polymer (2.0 eV) based on bithiazole for high efficiency polymer solar cells[J]. NANO ENERGY,2017,34:556-561. |
| APA | Guo, Bing.,Li, Wanbin.,Guo, Xia.,Meng, Xiangyi.,Ma, Wei.,...&Li, Yongfang.(2017).A novel wide bandgap conjugated polymer (2.0 eV) based on bithiazole for high efficiency polymer solar cells.NANO ENERGY,34,556-561. |
| MLA | Guo, Bing,et al."A novel wide bandgap conjugated polymer (2.0 eV) based on bithiazole for high efficiency polymer solar cells".NANO ENERGY 34(2017):556-561. |
入库方式： OAI收割
来源：化学研究所
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