Redox-responsive carbometalated ruthenium and osmium complexes
文献类型：期刊论文
| 作者 | Gong, Zhong-Liang1,2; Yao, Chang-Jiang1,2; Shao, Jiang-Yang1,2; Nie, Hai-Jing1,2; Tang, Jian-Hong1,2,3; Zhong, Yu-Wu1,2,3 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2017-05-01 |
| 卷号 | 60期号:5页码:583-590 |
| 关键词 | Stimuli-responsive Materials Electro-active Compounds Organometallic Materials Triarylamines Near-infrared Electrochromism |
| 英文摘要 | Organometallic conjugated complexes have become an important type of stimuli-responsive materials because of their appealing electrochemical properties and rich photonic, electronic, and magnetic properties. They are potentially useful in a wide range of applications such as molecular wires, molecular switches, molecular machines, molecular memory, and optoelectronic detections. This review outlines the recent progress on the molecular design of carbometalated ruthenium and osmium complexes and their applications as redox-responsive materials with visible and near-infrared (NIR) absorptions and electron paramagnetic resonance as readout signals. Three molecule systems are introduced, including the symmetric diruthenium complexes, metal-amine conjugated bi-center system, and multi-center redox-active organometallic compounds. Because of the presence of a metal-carbon bond on each metal component and strong electronic coupling between redox sites, these compounds display multiple reversible redox processes at low potentials and each redox state possesses significantly different physical and chemical properties. Using electrochemical potentials as input signals, these materials show reversible NIR absorption spectral changes, making them potentially useful in NIR electrochromism and information storage. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39049]  |
| 专题 | 化学研究所_光化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gong, Zhong-Liang,Yao, Chang-Jiang,Shao, Jiang-Yang,et al. Redox-responsive carbometalated ruthenium and osmium complexes[J]. SCIENCE CHINA-CHEMISTRY,2017,60(5):583-590. |
| APA | Gong, Zhong-Liang,Yao, Chang-Jiang,Shao, Jiang-Yang,Nie, Hai-Jing,Tang, Jian-Hong,&Zhong, Yu-Wu.(2017).Redox-responsive carbometalated ruthenium and osmium complexes.SCIENCE CHINA-CHEMISTRY,60(5),583-590. |
| MLA | Gong, Zhong-Liang,et al."Redox-responsive carbometalated ruthenium and osmium complexes".SCIENCE CHINA-CHEMISTRY 60.5(2017):583-590. |
入库方式： OAI收割
来源：化学研究所
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