中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Activation of Cellulose Assisted by CO2 for the Preparation of a Superhydrophobic Nanocoating

文献类型:期刊论文

作者Wang, Jinfang1; Xue, Zhimin2; Yu, Tingting1; Liu, Zhimin3; Mu, Tiancheng1
刊名CHEMISTRY-AN ASIAN JOURNAL
出版日期2017-07-18
卷号12期号:14页码:1773-1779
关键词Cellulose Dbu Activation Green Process Oil Water Separation Superhydrophobic Coatings
英文摘要There is increasing demand for superhydrophobic materials, which can be used for separating oil and water efficiently. To avoid secondary pollution, it is desirable to prepare such materials with green technology. Here, we present an environmentally benign method for fabricating superhydrophobic materials by using organic base based solvents in which cellulose can be dissolved and activated. The dissolved cellulose could be chemically modified with a silanization reagent, and the solvent could be recycled after CO2 was removed. The obtained cellulose nanocoating exhibited excellent hydrophobic effects. By spraying it on filter paper (water contact angle (WCA)=165 degrees) for oil and water separation, the separation efficiency of more than 95% was achieved; ultrasonication of an ordinary sponge in its dispersion (WCA=163 degrees), meant it could be used as an oil absorber. It can also absorb a certain amount of bisphenolA (BPA), with the concentration decreasing by 66% from the original concentration (0.1mm). Besides the high separation efficiency, it is resistant to a wide range of pH solutions, which means that it could be used in harsh environments. More importantly, the process is cost-effective, the solvent can be recycled, and the whole process is green. Thus, the activation method provides a green route for the preparation of other cellulose-based materials.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/39077]  
专题化学研究所_胶体、界面与化学热力学实验室
作者单位1.Renmin Univ China, Dept Chem, 59 Zhongguancun St, Beijing 100872, Peoples R China
2.Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, 35 Tsinghua East Rd, Beijing 100083, Peoples R China
3.Chinese Acad Sci, Inst Chem, BNLMS, 2 Zhongguancun Beiyijie, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Wang, Jinfang,Xue, Zhimin,Yu, Tingting,et al. Activation of Cellulose Assisted by CO2 for the Preparation of a Superhydrophobic Nanocoating[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(14):1773-1779.
APA Wang, Jinfang,Xue, Zhimin,Yu, Tingting,Liu, Zhimin,&Mu, Tiancheng.(2017).Activation of Cellulose Assisted by CO2 for the Preparation of a Superhydrophobic Nanocoating.CHEMISTRY-AN ASIAN JOURNAL,12(14),1773-1779.
MLA Wang, Jinfang,et al."Activation of Cellulose Assisted by CO2 for the Preparation of a Superhydrophobic Nanocoating".CHEMISTRY-AN ASIAN JOURNAL 12.14(2017):1773-1779.

入库方式: OAI收割

来源:化学研究所

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