Synthesis and Characterization of Tris(bidentate) Ruthenium Complexes of Di(pyrid-2-yl)(methyl)amine
文献类型：期刊论文
| 作者 | Wu, Si-Hai1; Shao, Jiang-Yang2; Dai, Xiaojuan2,3; Cui, Xiuling1; Su, Hongmei2,3,4; Zhong, Yu-Wu2,3 |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2017-06-30 |
| 期号 | 24页码:3064-3071 |
| 关键词 | Ruthenium n Ligands Coordination Modes Electrochemistry Photophysics |
| 英文摘要 | Three tris(bidentate) monoruthenium complexes [Ru(dpma)(bpy)(2)](PF6)(2) [1(PF6)(2); dpma = di(pyrid-2-yl)(methyl)-amine, bpy = 2,2'-bipyridine], [Ru(dpma)(2)(bpy)](PF6)(2) [2(PF6)(2)], and [Ru(dpma)(3)](PF6)(2) [3(PF6)(2)] with the electron-rich ligand dpma were synthesized and characterized. The single-crystal Xray structures of 1(PF6)(2) to 3(PF6)(2) are presented. The electro-chemical and spectroscopic properties of these complexes were examined and compared with those of the reference complex [Ru(bpy)(3)](PF6)(2). Complexes 1(PF6)(2) to 3(PF6)(2) show a decreased Ru-III/II redox potential by 140-310 mV with respect to [Ru(bpy)(3)](PF6)(2). The strong emission property of [Ru(bpy)(3)](PF6)(2) is maintained in 1(PF6)(2) and 2(PF6)(2). However, complex 3(PF6)(2) is only weakly emissive at room temperature. In addition, density functional theory (DFT) and time-dependent DFT calculations were performed to complement these experimental results. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39080]  |
| 专题 | 化学研究所_光化学实验室 |
| 作者单位 | 1.Huaqiao Univ, Sch Biomed Sci, Quanzhou 362021, Fujian, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Si-Hai,Shao, Jiang-Yang,Dai, Xiaojuan,et al. Synthesis and Characterization of Tris(bidentate) Ruthenium Complexes of Di(pyrid-2-yl)(methyl)amine[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2017(24):3064-3071. |
| APA | Wu, Si-Hai,Shao, Jiang-Yang,Dai, Xiaojuan,Cui, Xiuling,Su, Hongmei,&Zhong, Yu-Wu.(2017).Synthesis and Characterization of Tris(bidentate) Ruthenium Complexes of Di(pyrid-2-yl)(methyl)amine.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(24),3064-3071. |
| MLA | Wu, Si-Hai,et al."Synthesis and Characterization of Tris(bidentate) Ruthenium Complexes of Di(pyrid-2-yl)(methyl)amine".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .24(2017):3064-3071. |
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来源：化学研究所
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