Fast construction of dianthraceno[a,e]pentalenes for OPV applications
文献类型：期刊论文
| 作者 | Zhang, Zhongbo1,2; Fan, Haijun1; Zhu, Xiaozhang1,2 |
| 刊名 | ORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2017-05-01 |
| 卷号 | 4期号:5页码:711-716 |
| 英文摘要 | A new method based on a palladium-catalyzed tandem reaction for the fast construction of a dianthraceno[a,e] pentalene (DAP) framework is developed, which gave a series of dianthraceno[a,e] pentalenes with good functional group tolerance, and it should be highlighted that five C-C bonds were formed in one reaction. The photophysical and electrochemical properties of DAP derivatives were examined in detail. Interestingly, cross conjugation can be observed for DAPs substituted with electron-withdrawing substituents, which results in decreased optical bandgaps and the highest occupied molecular orbital (HOMO) energy levels. Because of the good absorption features, high fluorescence quantum yield and appropriate frontier energy levels, dianthraceno[a,e] pentalene with a p-((2-hexyldecyl)-2-cyanoacetate) phenyl group (DAP-PhCA) was utilized for solution-processed bulk-heterojunction solar cells, which delivered a power conversion efficiency of 2.05% with a high open-circuit voltage (Voc) value of 0.95 V. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39083]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhongbo,Fan, Haijun,Zhu, Xiaozhang. Fast construction of dianthraceno[a,e]pentalenes for OPV applications[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(5):711-716. |
| APA | Zhang, Zhongbo,Fan, Haijun,&Zhu, Xiaozhang.(2017).Fast construction of dianthraceno[a,e]pentalenes for OPV applications.ORGANIC CHEMISTRY FRONTIERS,4(5),711-716. |
| MLA | Zhang, Zhongbo,et al."Fast construction of dianthraceno[a,e]pentalenes for OPV applications".ORGANIC CHEMISTRY FRONTIERS 4.5(2017):711-716. |
入库方式： OAI收割
来源：化学研究所
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