中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Self-Assembled Chiral Nanostructures as Scaffolds for Asymmetric Reactions

文献类型:期刊论文

作者Jiang, Jian1; Ouyang, Guanghui2; Zhang, Li2; Liu, Minghua1,2
刊名CHEMISTRY-A EUROPEAN JOURNAL
出版日期2017-07-18
卷号23期号:40页码:9439-9450
关键词Asymmetric Reactions Chiral Nanostructures Micelles Nanocages Nanotubes
英文摘要The asymmetric reaction is one of the most important reactions in organic synthesis. While a large number of efficient molecular catalysts have been developed and applied, recently, supramolecular and nanostructured catalysts have been attracting interest. In this Minireview, we focus on self-assembled chiral nanostructures and review their possibility and feasibility as enantioselective catalysts. The design concept and the requirement of the chiral scaffold as the catalysts are discussed. Based on the chirality and catalytic performance of the building molecules and the supramolecular nanostructures, the nanocatalyst is divided into chiral nanostructure driven (CND) and chiral nanostructure enhanced (CNE) enantioselective catalysts. Then, several typical self-assembled chiral nanostructures such as nanocages, nanotubes, nanorods, micelles and vesicles are selected as the chiral scaffold and their catalytic behaviors for the asymmetric reactions were demonstrated. Finally, the future developments of the field are also discussed.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/39086]  
专题化学研究所_胶体、界面与化学热力学实验室
作者单位1.Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, Key Lab Nanosyst & Hierarch Fabricat, 11 ZhongGuanCun BeiYiTiao, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci BNLMS, Zhongguancun North First St 2, Beijing 100190, Peoples R China
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GB/T 7714
Jiang, Jian,Ouyang, Guanghui,Zhang, Li,et al. Self-Assembled Chiral Nanostructures as Scaffolds for Asymmetric Reactions[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017,23(40):9439-9450.
APA Jiang, Jian,Ouyang, Guanghui,Zhang, Li,&Liu, Minghua.(2017).Self-Assembled Chiral Nanostructures as Scaffolds for Asymmetric Reactions.CHEMISTRY-A EUROPEAN JOURNAL,23(40),9439-9450.
MLA Jiang, Jian,et al."Self-Assembled Chiral Nanostructures as Scaffolds for Asymmetric Reactions".CHEMISTRY-A EUROPEAN JOURNAL 23.40(2017):9439-9450.

入库方式: OAI收割

来源:化学研究所

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