Effects of optical-inert ions on upconversion luminescence and temperature sensing properties of ScVO4:10%Yb3+/2%Er3+ nano/micro-particles
文献类型：期刊论文
| 作者 | Li, Peng1; Guo, Linna1; Liang, Chenxi1; Li, Tiesheng1; Chen, Penglei2; Liu, Minghua2; Wu, Yangjie1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:81页码:51233-51244 |
| 英文摘要 | In this paper, ScVO4:10%Yb3+/2%Er3+ nano/micro-particles doped with optical-inert metal ions including the alkali metal ions (Li+/Na+/K+), alkaline-earth metal ions (Mg2+/Ca2+/Sr2+/Ba2+) and lanthanide ions (Y3+/Gd3+/Lu3+) were synthesized by a conventional solid-state method. X-ray diffraction studies show that the prepared ScVO4:10%Yb3+/2%Er3+ whether single-doping, codoping or tridoping optical-inert metal ions are highly crystalline in nature with tetragonal phase structure when the doping concentration <= 10%. Under a 980 nm laser diode excitation, the upconversion luminescence was enhanced significantly by single doping of Li+, Na+, K+, Mg2+, Ca2+, Sr2+, Ba2+, Y3+, Gd3+ or Lu3+, showing the strongest green emission with 5 mol% Li+ dopant. For codoping optical-inert metal ions system, it is found that Li+/Gd3+ couple is the most effective codopant, leading to an drastic increase of the UC luminescence centered at 554 nm by a factor of 15.3 compared to optical-inert metal ions free sample, while the factor of Li+/Ca2+/Gd3+ tridoping system is only 4.6. This work aims to investigate the origin of UC luminescence enhancement for ScVO4:10%Yb3+/2%Er3+ after codoping optical-inert ions based on the systematical analyses of the structures, morphologies, chemical states of elements, oxygen defects, optical absorption properties, etc. Furthermore, temperature-sensing performance was also investigated using the fluorescence intensity ratio technique. This opens a new window for studying the cooperation of the optical-inert ions doping effect on improving UC luminescence and temperature sensitivity properties. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39114]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Zhengzhou Univ, Key Lab Chem Biol & Organ Chem Henan Prov, Key Lab Nanoinformat Mat Zhengzhou, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Peng,Guo, Linna,Liang, Chenxi,et al. Effects of optical-inert ions on upconversion luminescence and temperature sensing properties of ScVO4:10%Yb3+/2%Er3+ nano/micro-particles[J]. RSC ADVANCES,2017,7(81):51233-51244. |
| APA | Li, Peng.,Guo, Linna.,Liang, Chenxi.,Li, Tiesheng.,Chen, Penglei.,...&Wu, Yangjie.(2017).Effects of optical-inert ions on upconversion luminescence and temperature sensing properties of ScVO4:10%Yb3+/2%Er3+ nano/micro-particles.RSC ADVANCES,7(81),51233-51244. |
| MLA | Li, Peng,et al."Effects of optical-inert ions on upconversion luminescence and temperature sensing properties of ScVO4:10%Yb3+/2%Er3+ nano/micro-particles".RSC ADVANCES 7.81(2017):51233-51244. |
入库方式： OAI收割
来源：化学研究所
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