Size-Dependent Reactivity of Nano-Sized Neutral Manganese Oxide Clusters toward Ethylene
文献类型：期刊论文
| 作者 | Chen, Jiao-Jiao1,2,3; Zhang, Ting1,2,3; Zhang, Mei-Qi1,2,3; Liu, Qing-Yu1,2; Li, Xiao-Na1,2; He, Sheng-Gui1,2,3 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2017-11-07 |
| 卷号 | 23期号:62页码:15820-15826 |
| 关键词 | Adsorption Gas Separation Manganese Nanostructures Reactivity Studies |
| 英文摘要 | Neutral manganese oxide clusters with the general composition Mn2NO3N+x (N=2-22; x=-1, 0, 1) with dimensions up to a nanosize were prepared by laser ablation and reacted with C2H4 in a fast flow reactor. The size-dependent reactivity of C2H4 adsorption on these clusters was experimentally identified and the adsorption reactivity decreases generally with an increase of the cluster size. Density functional theory calculations were performed to study the geometrical and electronic structures of the Mn2NO3N (N=1-6) clusters. The calculated results indicated that the coordination number and the charge distribution of the metal centers are responsible for the experimentally observed size-dependent reactivity. The highly charged Mn atoms with low coordination are preferential to adsorb C2H4. In contrast, the neutral manganese oxide clusters are completely inert toward the saturated hydrocarbon molecule C2H6. This work provides new perspectives to design related materials in the separation of hydrocarbon molecules. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39147]  |
| 专题 | 化学研究所_分子动态与稳态结构实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Jiao-Jiao,Zhang, Ting,Zhang, Mei-Qi,et al. Size-Dependent Reactivity of Nano-Sized Neutral Manganese Oxide Clusters toward Ethylene[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017,23(62):15820-15826. |
| APA | Chen, Jiao-Jiao,Zhang, Ting,Zhang, Mei-Qi,Liu, Qing-Yu,Li, Xiao-Na,&He, Sheng-Gui.(2017).Size-Dependent Reactivity of Nano-Sized Neutral Manganese Oxide Clusters toward Ethylene.CHEMISTRY-A EUROPEAN JOURNAL,23(62),15820-15826. |
| MLA | Chen, Jiao-Jiao,et al."Size-Dependent Reactivity of Nano-Sized Neutral Manganese Oxide Clusters toward Ethylene".CHEMISTRY-A EUROPEAN JOURNAL 23.62(2017):15820-15826. |
入库方式： OAI收割
来源：化学研究所
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