Spiro-Fused Perylene Diimide Arrays
文献类型：期刊论文
| 作者 | Gao, Guangpeng1; Liang, Ningning1,2; Geng, Hua1; Jiang, Wei1; Fu, Huiting1,2; Feng, Jiajing1,2; Hou, Jianhui1; Feng, Xinliang3,4; Wang, Zhaohui1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2017-11-08 |
| 卷号 | 139期号:44页码:15914-15920 |
| 英文摘要 | The straightforward palladium-catalyzed synthesis protocol toward spiro-fused perylene diimides is developed. The reaction involves two palladium-catalyzed C-H activations and 4-fold C-C bond formation sequence from readily available precursors. This facile and step-economic approach also provides another convenient access to ethylene-bridged dimer (NDP) and further pi-extended spiro system (SNTP). In addition, the molecular structure of spirodiperylenete-traimide (SDP) is illustrated to show a three-dimensional (3D) cruciform configuration, and its absorbance is distinctly red-shifted due to the significant spiroconjugation effect. With combined properties of broadened and intensive absorption, aligned LUMO levels, and unique molecular geometry, the spiro-fused PDI system represents a new kind of high-performance semiconducting framework as the electron acceptor in high-efficiency organic solar cells. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39151]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tech Univ Dresden, Ctr Advancing Elect Dresden, D-01062 Dresden, Germany 4.Tech Univ Dresden, Dept Chem & Food Chem, D-01062 Dresden, Germany |
| 推荐引用方式 GB/T 7714 | Gao, Guangpeng,Liang, Ningning,Geng, Hua,et al. Spiro-Fused Perylene Diimide Arrays[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(44):15914-15920. |
| APA | Gao, Guangpeng.,Liang, Ningning.,Geng, Hua.,Jiang, Wei.,Fu, Huiting.,...&Wang, Zhaohui.(2017).Spiro-Fused Perylene Diimide Arrays.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(44),15914-15920. |
| MLA | Gao, Guangpeng,et al."Spiro-Fused Perylene Diimide Arrays".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.44(2017):15914-15920. |
入库方式： OAI收割
来源：化学研究所
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