Mixed Phthalocyanine-Porphyrin Fused Conjugated Pentameric Nanoarrays
文献类型：期刊论文
| 作者 | Zhang, Yuehong1; Xue, Zheng2; Qi, Dongdong1; Wang, Kang1; Liu, Huibiao2,3; Jiang, Jianzhuang1 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2017-10-26 |
| 卷号 | 23期号:60页码:15017-15021 |
| 关键词 | Nanorods Phthalocyanine Porphyrins Saddle Conformation Semiconductivity |
| 英文摘要 | The largest phthalocyanine-porphyrin-fused pentameric molecular arrays have been synthesized and spectroscopically characterized. The saddled molecular conformation revealed for the pentamer by DFT-D3 calculation in combination with the bulky peripheral substituents precludes effective face-to-face - intermolecular interaction. As a consequence, intermolecular C-H interactions together with the ubiquitous dispersion force arrays help to self-assemble the representative metal-free pentameric molecules into the three-dimensional supramolecular structures with nanorod morphology in CHCl3 and n-butanol. Powder X-ray diffraction (XRD) analysis and selected area electron diffraction (SAED) disclose the gradually increased long range of molecular ordering in the nanorods along with the increase in the substrate temperature from 30, 40, 50, to 60 degrees C. This in turn results in an increase in the semiconductivity of the single nanorod in the same order from 9.4x10(-9) to 3.8x10(-8), 7.6x10(-7), and 6.3x10(-5)Sm(-1). |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39177]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Univ Sci & Technol Beijing, Dept Chem, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Organ Solids,BNLMS, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yuehong,Xue, Zheng,Qi, Dongdong,et al. Mixed Phthalocyanine-Porphyrin Fused Conjugated Pentameric Nanoarrays[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017,23(60):15017-15021. |
| APA | Zhang, Yuehong,Xue, Zheng,Qi, Dongdong,Wang, Kang,Liu, Huibiao,&Jiang, Jianzhuang.(2017).Mixed Phthalocyanine-Porphyrin Fused Conjugated Pentameric Nanoarrays.CHEMISTRY-A EUROPEAN JOURNAL,23(60),15017-15021. |
| MLA | Zhang, Yuehong,et al."Mixed Phthalocyanine-Porphyrin Fused Conjugated Pentameric Nanoarrays".CHEMISTRY-A EUROPEAN JOURNAL 23.60(2017):15017-15021. |
入库方式： OAI收割
来源：化学研究所
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