Microwave-Assisted thiol-ene click chemistry of carbon nanoforms
文献类型：期刊论文
| 作者 | Peng, Zhongchuan1,2; Li, Huayi1; Li, Qian1; Hu, Youliang1 |
| 刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| 出版日期 | 2017-11-20 |
| 卷号 | 533页码:48-54 |
| 关键词 | Microwave Fullerene Carbon Nanotube Graphene Thoil-ene |
| 英文摘要 | Carbon nanoforms (CNFs, including graphene, carbon nanotube and fullerene) were functionalized via microwave- assisted thiol-ene click chemistry. Different functional CNFs with -COOH, -NH2, -NH3Cl,-Si(OCH3)(3), alkyl and furyl groups were obtained and characterized by XPS, EDS, TGA, Raman spectroscopy and MALDI-TOF MS. Microwave was much more efficient to promote reactions than traditional thermal method. XPS confirmed the binding energy of C-S-C (163.3ev) the modified CNFs. Raman spectroscopy showed increasing I-D/I-G and A(D)/A(G) of graphene and CNT after thiol-ene addition reaction. The result of MALDI-TOF MS indicated that the thiol-containing molecules were attached on fullerene. All these results indicated the successful thiol-ene click reactions between CNFs and thiol-containing molecules under microwave. TGA analysis results showed the mass loss of the modified CNFs, which provided that AIBN and 3-merlaptopropionic acid were the most efficient initiator and monomer, respectively. In summary, the microwave-assisted thiol-ene click reaction provided a powerful chemical tool for the preparation of functional CNFs materials. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39182]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Zhongchuan,Li, Huayi,Li, Qian,et al. Microwave-Assisted thiol-ene click chemistry of carbon nanoforms[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2017,533:48-54. |
| APA | Peng, Zhongchuan,Li, Huayi,Li, Qian,&Hu, Youliang.(2017).Microwave-Assisted thiol-ene click chemistry of carbon nanoforms.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,533,48-54. |
| MLA | Peng, Zhongchuan,et al."Microwave-Assisted thiol-ene click chemistry of carbon nanoforms".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 533(2017):48-54. |
入库方式： OAI收割
来源：化学研究所
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