Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals
文献类型：期刊论文
| 作者 | Gong, Yanjun1,3; Zhang, Yifan4; Xiong, Wei1,3; Zhang, Ke2,3; Che, Yanke1,3; Zhao, Jincai1,3 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2017-08-09 |
| 卷号 | 139期号:31页码:10649-10652 |
| 英文摘要 | In this work, we fabricated four diphenylcyclopropenone (DPCP) crystals, which involved various molecular interactions encoded in individual molecular structures 1-4. On the basis of crystalline structural analysis and photoresponsive characterization of the resultant single-crystal microribbons 1-4, we demonstrated that the magnitude of molecular interactions could effectively control the quantum chain reaction and the photoresponsive property of the DPCP crystals. The microribbons 1 and 2 having weak molecular interactions exhibited an efficient chain reaction and large mechanical photoresponses (i.e., photomelting and photodeforming), whereas the microribbons 3 and 4 with strong molecular interactions exhibited no chain reaction and mechanical morphology change. Our work presented a new way to achieve molecular crystals with enhanced mechanical photoresponses. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39200]  |
| 专题 | 化学研究所_光化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Ulsan Natl Inst Sci & Technol, IBS Ctr Soft & Living Matter, Ulsan 689789, South Korea |
| 推荐引用方式 GB/T 7714 | Gong, Yanjun,Zhang, Yifan,Xiong, Wei,et al. Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(31):10649-10652. |
| APA | Gong, Yanjun,Zhang, Yifan,Xiong, Wei,Zhang, Ke,Che, Yanke,&Zhao, Jincai.(2017).Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(31),10649-10652. |
| MLA | Gong, Yanjun,et al."Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.31(2017):10649-10652. |
入库方式： OAI收割
来源：化学研究所
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