Template synthesis of imine-based covalent organic framework core-shell structure and hollow sphere: a case of COFTTA-DHTA
文献类型：期刊论文
| 作者 | Sun, Bing1,2; Wang, Dong1,2; Wan, Lijun1 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2017-08-01 |
| 卷号 | 60期号:8页码:1098-1102 |
| 关键词 | Covalent Organic Framework Template Synthesis Organic Porous Material Core-shell Structure Hollow Sphere |
| 英文摘要 | Controllably synthesizing well-dispersed covalent organic frameworks (COFs) with uniform both morphology and size is still a challenge. Herein, we report the template-directed synthesis of COFTTA-DHTA-based core-shell hybrids under solvothermal conditions by using amino-functionalized SiO2 microspheres as templates coupled with stepwise addition of initial monomer molecules. The modified amino groups on the surfaces of SiO2 templates play an important role in the formation of well-defined NH2-f-SiO2@COFTTA-DHTA core-shell hybrids. COFTTA-DHTA hollow spheres can be obtained by etching SiO2 cores of NH2-f-SiO2@COFTTA-DHTA. Both the NH2-f-SiO2@COFTTA-DHTA and COFTTA-DHTA hollow spheres possess the well-defined morphology, high crystallinity and porosity, excellent dispersion property and high chemical stability. The template synthesis method demonstrated in this work provides a general method for the shape-controlled synthesis of COF-based materials, which is important for the further applications in the fields such as energy storage, drug delivery and catalysis. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39221]  |
| 专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Bing,Wang, Dong,Wan, Lijun. Template synthesis of imine-based covalent organic framework core-shell structure and hollow sphere: a case of COFTTA-DHTA[J]. SCIENCE CHINA-CHEMISTRY,2017,60(8):1098-1102. |
| APA | Sun, Bing,Wang, Dong,&Wan, Lijun.(2017).Template synthesis of imine-based covalent organic framework core-shell structure and hollow sphere: a case of COFTTA-DHTA.SCIENCE CHINA-CHEMISTRY,60(8),1098-1102. |
| MLA | Sun, Bing,et al."Template synthesis of imine-based covalent organic framework core-shell structure and hollow sphere: a case of COFTTA-DHTA".SCIENCE CHINA-CHEMISTRY 60.8(2017):1098-1102. |
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来源：化学研究所
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