Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step
文献类型：期刊论文
| 作者 | Gong, Yuanzheng1; Yang, Chun1; Ji, Hongwei1; Chen, Chuncheng1; Ma, Wanhong1,2; Zhao, Jincai1,2 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2017-08-17 |
| 卷号 | 12期号:16页码:2048-2051 |
| 关键词 | h(Vb)(+)/(Oh)-o-center Dot Oxidation Hydroxylation Of Aromatics Inverse Kinetic Isotope Effect Rate-determining Step Tio2 Photocatalysis |
| 英文摘要 | In aqueous TiO2 photocatalytic hydroxylation of weakly polar aromatics, a series of inverse H/D KIEs of 0.7-0.8 were observed, which is different than the normal H/D kinetic isotope effects (KIEs) usually observed for polar aromatics. This result indicated that the oxidation started by photo-induced h(vb)(+) can be the rate-determining step. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39315]  |
| 专题 | 化学研究所_光化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Photochem, Natl Lab Mol Sci, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gong, Yuanzheng,Yang, Chun,Ji, Hongwei,et al. Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(16):2048-2051. |
| APA | Gong, Yuanzheng,Yang, Chun,Ji, Hongwei,Chen, Chuncheng,Ma, Wanhong,&Zhao, Jincai.(2017).Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step.CHEMISTRY-AN ASIAN JOURNAL,12(16),2048-2051. |
| MLA | Gong, Yuanzheng,et al."Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step".CHEMISTRY-AN ASIAN JOURNAL 12.16(2017):2048-2051. |
入库方式： OAI收割
来源：化学研究所
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