Precise Manipulation of Multilength Scale Morphology and Its Influence on Eco-Friendly Printed All-Polymer Solar Cells
文献类型：期刊论文
| 作者 | Ye, Long1; Xiong, Yuan1; Li, Sunsun2; Ghasemi, Masoud1; Balar, Nrup3,4; Turner, Johnathan1; Gadisa, Abay1; Hou, Jianhui2; O'Connor, Brendan T.3,4; Ade, Harald1 |
| 刊名 | ADVANCED FUNCTIONAL MATERIALS
 |
| 出版日期 | 2017-09-06 |
| 卷号 | 27期号:33 |
| 关键词 | Green Solvents Multilength Morphology Nonfullerene Solar Cells Polymer Blends Solvent Additives |
| 英文摘要 | Significant efforts have lead to demonstrations of nonfullerene solar cells (NFSCs) with record power conversion efficiency up to approximate to 13% for polymer: small molecule blends and approximate to 9% for all-polymer blends. However, the control of morphology in NFSCs based on polymer blends is very challenging and a key obstacle to pushing this technology to eventual commercialization. The relations between phases at various length scales and photovoltaic parameters of all-polymer bulk-heterojunctions remain poorly understood and seldom explored. Here, precise control over a multilength scale morphology and photovoltaic performance are demonstrated by simply altering the concentration of a green solvent additive used in blade-coated films. Resonant soft X-ray scattering is used to elucidate the multiphasic morphology of these printed all-polymeric films and complements with the use of grazing incidence wide-angle X-ray scattering and in situ spectroscopic ellipsometry characterizations to correlate the morphology parameters at different length scales to the device performance metrics. Benefiting from the highest relative volume fraction of small domains, additive-free solar cells show the best device performance, strengthening the advantage of single benign solvent approach. This study also highlights the importance of high volume fraction of smallest domains in printed NFSCs and organic solar cells in general. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39327]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.North Carolina State Univ, Dept Phys, Organ & Carbon Elect Lab ORaCEL, Raleigh, NC 27695 USA 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 3.North Carolina State Univ, Dept Mech & Aerosp Engn, Raleigh, NC 27695 USA 4.North Carolina State Univ, ORaCEL, Raleigh, NC 27695 USA |
| 推荐引用方式 GB/T 7714 | Ye, Long,Xiong, Yuan,Li, Sunsun,et al. Precise Manipulation of Multilength Scale Morphology and Its Influence on Eco-Friendly Printed All-Polymer Solar Cells[J]. ADVANCED FUNCTIONAL MATERIALS,2017,27(33). |
| APA | Ye, Long.,Xiong, Yuan.,Li, Sunsun.,Ghasemi, Masoud.,Balar, Nrup.,...&Ade, Harald.(2017).Precise Manipulation of Multilength Scale Morphology and Its Influence on Eco-Friendly Printed All-Polymer Solar Cells.ADVANCED FUNCTIONAL MATERIALS,27(33). |
| MLA | Ye, Long,et al."Precise Manipulation of Multilength Scale Morphology and Its Influence on Eco-Friendly Printed All-Polymer Solar Cells".ADVANCED FUNCTIONAL MATERIALS 27.33(2017). |
入库方式： OAI收割
来源：化学研究所
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