Chemoselective and Enantioselective Hydrogenation of 2,4-Diaryl-3H-benzo[b]azepines Catalyzed by Dendritic Phosphinooxazoline Iridium Complexes
文献类型：期刊论文
| 作者 | Miao, Tingting1,2,3; Ma, Baode1,2,3; Ding, Ziyuan1,2,3; Liu, Youran1,2,3; He, Yan-Mei1,2,3; Fan, Qing-Hua1,2,3 |
| 刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2017-09-01 |
| 卷号 | 6期号:9页码:1219-1221 |
| 关键词 | Asymmetric Catalysis Benzo[b]Azepine Dendrimers Hydrogenation n p Ligands |
| 英文摘要 | An asymmetric hydrogenation of 2,4-diaryl-3H-benzo[b]azepines, catalyzed by dendritic phosphinooxazoline (PHOX) iridium complexes, has been developed. Only the imine group was reduced, while the C=C bond remained untouched, affording a range of chiral 2,3-dihydro-1H-benzo[b]azepine derivatives with good to excellent enantioselectivity (up to 91% ee). A slightly positive dendritic effect on catalytic reactivity (up to 10000TON) was observed. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41048]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100190, Peoples R China 3.Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Miao, Tingting,Ma, Baode,Ding, Ziyuan,et al. Chemoselective and Enantioselective Hydrogenation of 2,4-Diaryl-3H-benzo[b]azepines Catalyzed by Dendritic Phosphinooxazoline Iridium Complexes[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2017,6(9):1219-1221. |
| APA | Miao, Tingting,Ma, Baode,Ding, Ziyuan,Liu, Youran,He, Yan-Mei,&Fan, Qing-Hua.(2017).Chemoselective and Enantioselective Hydrogenation of 2,4-Diaryl-3H-benzo[b]azepines Catalyzed by Dendritic Phosphinooxazoline Iridium Complexes.ASIAN JOURNAL OF ORGANIC CHEMISTRY,6(9),1219-1221. |
| MLA | Miao, Tingting,et al."Chemoselective and Enantioselective Hydrogenation of 2,4-Diaryl-3H-benzo[b]azepines Catalyzed by Dendritic Phosphinooxazoline Iridium Complexes".ASIAN JOURNAL OF ORGANIC CHEMISTRY 6.9(2017):1219-1221. |
入库方式： OAI收割
来源：化学研究所
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