Regioirregular Ambipolar Naphthalenediimide-Based Alternating Polymers: Synthesis, Characterization, and Application in Field-Effect Transistors
文献类型：期刊论文
| 作者 | Lin, Zuzhang1; Liu, Xiaotong2; Zhang, Weifeng2; Wei, Congyuan2; Huang, Jianyao2; Chen, Zhihui2; Wang, Liping1; Yu, Gui2,3 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2017-11-01 |
| 卷号 | 55期号:21页码:3627-3635 |
| 关键词 | Ambipolar Carrier Transport Asymmetric Units Field-effect Transistors Naphthalenediimide Polymer Semiconductors |
| 英文摘要 | In this work, we report the synthesis, characterization, and application of two regioirregular naphthalenediimide (NDI)-based alternating conjugated polymers, namely P1 and P2, in which nitrile-substituted moiety, 2,3-bis(thiophen-2-yl)acrylonitrile and NDI moiety act as donor and acceptor unit, respectively. The two regioirregular polymers possess low-lying LUMO energy levels of -3.92 eV for P1 and -3.96 eV for P2. Both polymers possess typical dual-band UV-Vis-NIR absorption profiles of NDI-based polymers, and show broadened and red-shifted absorption spectra in the solid state compared with those in solutions. Field-effect transistor devices with top-gate bottom-contact configuration were used to evaluate the polymers' semiconducting properties. The two polymers exhibited promising and air-stable ambipolar charge transport characteristics. Thin film microstructure investigations (AFM and 2D-GIXRD) suggest both polymers formed continuous and smooth thin films, and adopted predominantly face-on molecular packing in the solid state. (c) 2017 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41059]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Chem, Organ Solids Lab, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Zuzhang,Liu, Xiaotong,Zhang, Weifeng,et al. Regioirregular Ambipolar Naphthalenediimide-Based Alternating Polymers: Synthesis, Characterization, and Application in Field-Effect Transistors[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2017,55(21):3627-3635. |
| APA | Lin, Zuzhang.,Liu, Xiaotong.,Zhang, Weifeng.,Wei, Congyuan.,Huang, Jianyao.,...&Yu, Gui.(2017).Regioirregular Ambipolar Naphthalenediimide-Based Alternating Polymers: Synthesis, Characterization, and Application in Field-Effect Transistors.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,55(21),3627-3635. |
| MLA | Lin, Zuzhang,et al."Regioirregular Ambipolar Naphthalenediimide-Based Alternating Polymers: Synthesis, Characterization, and Application in Field-Effect Transistors".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 55.21(2017):3627-3635. |
入库方式： OAI收割
来源：化学研究所
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