Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior
文献类型：期刊论文
| 作者 | Yuan, Shi-Fang1; Duan, Ting2; Wang, Lijing2; Wei, Xuehong1; Wang, Xinxin3; Sun, Wen-Hua3
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| 刊名 | INORGANICA CHIMICA ACTA
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| 出版日期 | 2017-09-01 |
| 卷号 | 466页码:497-501 |
| 关键词 | Azaallylzirconium Oxo-bridged Ethylene Polymerization Synthesis Characterization |
| 英文摘要 | The oxo-bridged azaallylzirconium chlorides (mu-O){eta(3)-(2,6-Et-2-4-R-C6H2) N(Ph) CCHSiMe2NMe2ZrCl2}(2), [R = Me (C1) and H (C2)] have been prepared in reasonable yields from the reactions of zirconium tetrachloride and the correspondent ligands, Me2NMe2SiCH2(Ph)CN(2,6-Et-2-4-R-C6H2). The representative complex C1 was crystallized and identified by the single-crystal X-ray diffraction, indicating oxo-bridged dinuclear azaallylzirconium structure. Both azaallylzirconium complexes exhibited notable catalytic activities toward ethylene polymerization in the presence of MAO, and obtained polyethylenes possess high molecular weights. (C) 2017 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41077]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Shanxi Univ, Inst Appl Chem, Taiyuan 030006, Shanxi, Peoples R China 2.Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Shi-Fang,Duan, Ting,Wang, Lijing,et al. Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior[J]. INORGANICA CHIMICA ACTA,2017,466:497-501. |
| APA | Yuan, Shi-Fang,Duan, Ting,Wang, Lijing,Wei, Xuehong,Wang, Xinxin,&Sun, Wen-Hua.(2017).Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior.INORGANICA CHIMICA ACTA,466,497-501. |
| MLA | Yuan, Shi-Fang,et al."Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior".INORGANICA CHIMICA ACTA 466(2017):497-501. |
入库方式： OAI收割
来源：化学研究所
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