Chiral six-coordinate Dy(III) and Tb(III) complexes of an achiral ligand: structure, fluorescence, and magnetism
文献类型：期刊论文
| 作者 | Liu, Mei-Jiao1; Yuan, Juan1; Zhang, Yi-Quan2; Sun, Hao-Ling3,4; Liu, Cai-Ming5; Kou, Hui-Zhong1 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2017-10-14 |
| 卷号 | 46期号:38页码:13035-13042 |
| 英文摘要 | Two new chiral six-coordinate lanthanide complexes (1 for Dy and 2 for Tb) have been synthesized using the achiral flexible ligand H2L (2,2'-[1,2-ethanediylbis[(methylimino) methylene]] bis[4,5-dimethylphenol]). Both complexes crystallize in the chiral P1 group space, and the enantiomers [Zn(L)Cl](3)Dy center dot MeOH center dot 0.5H(2)O (Lambda-1), [Zn(L) Cl](3)Dy center dot 1.5H(2)O (triangle-1), [Zn(L)Cl](3)Tb center dot 1.5H(2)O (Lambda-2) and [Zn(L)Cl](3)Tb center dot H2O (triangle-2) are isolated in the reaction. Three [Zn(L) Cl](-) anions coordinate to the central lanthanide ion using two phenoxo oxygen atoms of L2-, and the lanthanide ion has the coordination geometry of D-3. Complex 1 exhibits a field-induced slow magnetization relaxation, which is typical of a single-ion magnet (SIM). Ab initio calculations on complex 1 and studies on magneto-structural correlationship of six-coordinate Dy(III) SIMs indicate that the small energy barrier of complex 1 might be related to the absence of a unique anisotropic axis for the regular octahedral coordination configuration of Dy(III) and the high quantum tunneling gap between the ground states (m(J) = +/- 15/2). Complex 2 displays green photofluorescence and triboluminescence. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41087]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Nanjing Normal Univ, Sch Phys Sci & Technol, Jiangsu Key Lab NSLSCS, Nanjing 210023, Jiangsu, Peoples R China 3.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China 4.Beijing Normal Univ, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China 5.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Mei-Jiao,Yuan, Juan,Zhang, Yi-Quan,et al. Chiral six-coordinate Dy(III) and Tb(III) complexes of an achiral ligand: structure, fluorescence, and magnetism[J]. DALTON TRANSACTIONS,2017,46(38):13035-13042. |
| APA | Liu, Mei-Jiao,Yuan, Juan,Zhang, Yi-Quan,Sun, Hao-Ling,Liu, Cai-Ming,&Kou, Hui-Zhong.(2017).Chiral six-coordinate Dy(III) and Tb(III) complexes of an achiral ligand: structure, fluorescence, and magnetism.DALTON TRANSACTIONS,46(38),13035-13042. |
| MLA | Liu, Mei-Jiao,et al."Chiral six-coordinate Dy(III) and Tb(III) complexes of an achiral ligand: structure, fluorescence, and magnetism".DALTON TRANSACTIONS 46.38(2017):13035-13042. |
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来源：化学研究所
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