High-performance nonfullerene polymer solar cells with open-circuit voltage over 1 V and energy loss as low as 0.54 eV
文献类型：期刊论文
| 作者 | Fan, Qunping1; Xu, Zhuo1; Guo, Xia1; Meng, Xiangyi2; Li, Wanbin1; Su, Wenyan1; Ou, Xuemei1; Ma, Wei2; Zhang, Maojie1; Li, Yongfang1,3 |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2017-10-01 |
| 卷号 | 40页码:20-26 |
| 关键词 | Nonfullerene Polymer Solar Cells High Open-circuit Voltage Low Energy Loss Wide-bandgap Copolymer |
| 英文摘要 | In this work, we developed high efficiency nonfullerene PSCs based on a wide bandgap polymer donor PBPD-Th with a structure of meta-alkoxyphenyl benzodithiophene-alt-thienyl benzodithiophene-4,8-dione and a low bandgap small molecule acceptor ITIC. The PBPD-Th shows a strong absorption in the short wavelength of 300-650 nm with a bandgap of 1.91 eV, which is complementary with that of ITIC (1.55 eV). Moreover, PBPD-Th possesses a deep HOMO level of -5.42 eV, which is beneficial to obtain high open-circuit voltage (V-oc) in PSCs. As a result, the optimal PSCs based on PBPD-Th: ITIC showed a power conversion efficiency (PCE) of 10.8% with a V-oc of up to 1.01 V, a high short-circuit current density (J(sc)) of 18.3 mA cm(-2) and a fill factor (FF) of 59%, under the illumination of AM 1.5 G, 100 mW cm(-2). Notably, the energy loss (E-loss) of the optimal PSCs is 0.54 eV, which is smaller than the empirically low threshold of 0.6 eV. The PCE of 10.8% is one of the highest values reported in the literatures for the PSCs with Voc over 1.0 V. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41094]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Lab Adv Optoelect Mat, State & Local Joint Engn,Lab Novel Funct Polymer, Suzhou 215123, Peoples R China 2.Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Qunping,Xu, Zhuo,Guo, Xia,et al. High-performance nonfullerene polymer solar cells with open-circuit voltage over 1 V and energy loss as low as 0.54 eV[J]. NANO ENERGY,2017,40:20-26. |
| APA | Fan, Qunping.,Xu, Zhuo.,Guo, Xia.,Meng, Xiangyi.,Li, Wanbin.,...&Li, Yongfang.(2017).High-performance nonfullerene polymer solar cells with open-circuit voltage over 1 V and energy loss as low as 0.54 eV.NANO ENERGY,40,20-26. |
| MLA | Fan, Qunping,et al."High-performance nonfullerene polymer solar cells with open-circuit voltage over 1 V and energy loss as low as 0.54 eV".NANO ENERGY 40(2017):20-26. |
入库方式： OAI收割
来源：化学研究所
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