A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis
文献类型：期刊论文
| 作者 | Yang, Shuliang1,2; Zhu, Yanan1,2; Cao, Changyan1,2; Peng, Li3; Li, Shumu1; Zhai, Dowei1,2; Song, Weiguo1,2 |
| 刊名 | NANOSCALE
 |
| 出版日期 | 2017-09-28 |
| 卷号 | 9期号:36页码:13538-13545 |
| 英文摘要 | The construction of core-shell structures through surface coating, and then making use of the synergistic effects between the core and shell to design and synthesize heterogeneous catalysts is a hot topic in the heterogeneous catalysis field. Developing a general coating route with functional shell materials is further highly desirable. Here we found that a poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) layer can be generally coated on various substrates with different components and morphologies, including metal oxides, noble metal nanoparticles, carbon materials and metal-organic frameworks (MOFs). In addition, the coating thickness could be well controlled through simply adjusting the amount of monomers. Taking advantage of the heteroatoms in the PZS layer and the synergistic effect between the core and shell, new methods for fabrication of co-doped hollow carbon shell catalysts and transition metal phosphide nanoparticles were developed. As a proof-of-concept application, the N, P, S-doped hollow carbon shells prepared by calcination of a ZnCo-ZIFs@PZS core-shell structure could act as a good carbo-catalyst for selective oxidation of C-H bonds in water. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41113]  |
| 专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.EPFL ISIC Valais, Inst Chem Sci & Engn, CH-1950 Sion, Switzerland |
| 推荐引用方式 GB/T 7714 | Yang, Shuliang,Zhu, Yanan,Cao, Changyan,et al. A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis[J]. NANOSCALE,2017,9(36):13538-13545. |
| APA | Yang, Shuliang.,Zhu, Yanan.,Cao, Changyan.,Peng, Li.,Li, Shumu.,...&Song, Weiguo.(2017).A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis.NANOSCALE,9(36),13538-13545. |
| MLA | Yang, Shuliang,et al."A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis".NANOSCALE 9.36(2017):13538-13545. |
入库方式： OAI收割
来源：化学研究所
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