中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Simultaneous structure and luminescence property control of barium carbonate nanocrystals through small amount of lanthanide doping

文献类型:期刊论文

作者Gu, Jianmin1; Bian, Zhenpan1; Yin, Baipeng1; Jin, Cuihong1; Liu, Xin1; Gao, Yahui1; Wu, Jingxiao1; Tang, Shoufeng1; Gao, Faming1; Zhao, Yong Sheng2
刊名SCIENCE BULLETIN
出版日期2017-09-30
卷号62期号:18页码:1239-1244
关键词Lanthanide Doping Small Amount Of Doping Structure Control Luminescence Property Barium Carbonate Nanocrystals
英文摘要Rare earth doping has been widely applied in many functional nanomaterials with desirable properties and functions, which would have a significant effect on the growth process of the materials. However, the controlling strategy is limited into high concentration of lanthanide doping, which produces concentration quenching of the lanthanide ion luminescence with an increase in the Ln(3+) concentration, resulting in lowering the fluorescence quantum yield of lanthanide ion. Herein, for the first time, we demonstrate simultaneous control of the structures and luminescence properties of BaCO3 nanocrystals via a small amount of Tb3+ doping strategy. In fact, Tb3+ would partially occupy Ba2+ sites, resulting in the changes to the structures of the BaCO3 nanocrystals, which is primarily determined by charge modulation, including the contributions from the surfaces of crystal nuclei and building blocks. These structurally modified nanocrystals exhibit tunable luminescence properties, thus emerging as potential candidates for photonic devices such as light-emitting diodes and color displays. (C) 2017 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/41114]  
专题化学研究所_光化学实验室
作者单位1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Gu, Jianmin,Bian, Zhenpan,Yin, Baipeng,et al. Simultaneous structure and luminescence property control of barium carbonate nanocrystals through small amount of lanthanide doping[J]. SCIENCE BULLETIN,2017,62(18):1239-1244.
APA Gu, Jianmin.,Bian, Zhenpan.,Yin, Baipeng.,Jin, Cuihong.,Liu, Xin.,...&Zhao, Yong Sheng.(2017).Simultaneous structure and luminescence property control of barium carbonate nanocrystals through small amount of lanthanide doping.SCIENCE BULLETIN,62(18),1239-1244.
MLA Gu, Jianmin,et al."Simultaneous structure and luminescence property control of barium carbonate nanocrystals through small amount of lanthanide doping".SCIENCE BULLETIN 62.18(2017):1239-1244.

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来源:化学研究所

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