Conjugated Polymer with Intrinsic Alkyne Units for Synergistically Enhanced Raman Imaging in Living Cells
文献类型:期刊论文
作者 | Li, Shengliang1; Chen, Tao2; Wang, Yunxia1; Liu, Libing1; Lv, Fengting1; Li, Zhiliang3; Huang, Yanyi2; Schanze, Kirk S.3; Wang, Shu1 |
刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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出版日期 | 2017-10-16 |
卷号 | 56期号:43页码:13455-13458 |
关键词 | Living Cells Nanoparticles Poly(Phenylene Ethynylene) Raman Imaging |
英文摘要 | Development of Raman-active materials with enhanced and distinctive Raman vibrations in the Raman-silent region (1800-2800cm(-1)) is highly required for specific molecular imaging of living cells with high spatial resolution. Herein, water-soluble cationic conjugated polymers (CCPs), poly(phenylene ethynylene) (PPE) derivatives, are explored for use as alkyne-state-dependent Raman probes for living cell imaging due to synergetic enhancement effect of alkyne vibrations in Raman-silent region compared to alkyne-containing small molecules. The enhanced alkyne signals result from the integration of alkyne groups into the rigid backbone and the delocalized pi-conjugated structure. PPE-based conjugated polymer nanoparticles (CPNs) were also prepared as Raman-responsive nanomaterials for distinct imaging application. This work opens a new way into the development of conjugated polymer materials for enhanced Raman imaging. |
语种 | 英语 |
源URL | [http://ir.iccas.ac.cn/handle/121111/41258] ![]() |
专题 | 化学研究所_有机固体实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Peking Univ, Biodynam Opt Imaging Ctr, Coll Engn, Beijing 100871, Peoples R China 3.Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA |
推荐引用方式 GB/T 7714 | Li, Shengliang,Chen, Tao,Wang, Yunxia,et al. Conjugated Polymer with Intrinsic Alkyne Units for Synergistically Enhanced Raman Imaging in Living Cells[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(43):13455-13458. |
APA | Li, Shengliang.,Chen, Tao.,Wang, Yunxia.,Liu, Libing.,Lv, Fengting.,...&Wang, Shu.(2017).Conjugated Polymer with Intrinsic Alkyne Units for Synergistically Enhanced Raman Imaging in Living Cells.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(43),13455-13458. |
MLA | Li, Shengliang,et al."Conjugated Polymer with Intrinsic Alkyne Units for Synergistically Enhanced Raman Imaging in Living Cells".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.43(2017):13455-13458. |
入库方式: OAI收割
来源:化学研究所
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