Trichalcogenasumanene ortho-Quinones: Synthesis, Properties, and Transformation into Various Heteropolycycles
文献类型：期刊论文
| 作者 | Sun, Yantao1; Li, Xuexiang1; Sun, Chunlin1; Shen, Hongguang2; Hou, Xueqing1; Lin, Dongxu1; Zhang, Hao-Li1; Di, Chong-an2; Zhu, Daoben2; Shao, Xiangfeng1 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-10-16 |
| 卷号 | 56期号:43页码:13470-13474 |
| 关键词 | Conjugation Organic Semiconductors Sensors Solid-state Emission Trichalcogenasumanenes |
| 英文摘要 | The regioselective transformation of heterobuckybowl trichalcogenasumanenes 1 a,b at peripheral butoxy groups afforded trichalcogenasumanene ortho-quinones 2 a,b. Compounds 2 a,b are distinct from 1 a,b in terms of their molecular geometry and electronic state; that is, they have a shallower bowl depth and show absorbance in the NIR region. The reaction of 2 a,b with diamines resulted in a variety of heteropolycycles, including molecular spoon 3 a-6a, planar pi-systems 3 b-6b, and highly twisted [7-6-6]-fused systems 7 a,b. These new heteropolycycles had different optical/electrical properties: 4 a,b showed hole mobility of approximately 0.002cm(2)V(-1)s(-1), 6a displayed red emission in both solution and the solid state, and 7 a,b formed tight stacks of the curved pi-surface. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41262]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Tianshui Southern Rd 222, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Key Lab Organ Solids, Inst Chem, Beijing 100180, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yantao,Li, Xuexiang,Sun, Chunlin,et al. Trichalcogenasumanene ortho-Quinones: Synthesis, Properties, and Transformation into Various Heteropolycycles[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(43):13470-13474. |
| APA | Sun, Yantao.,Li, Xuexiang.,Sun, Chunlin.,Shen, Hongguang.,Hou, Xueqing.,...&Shao, Xiangfeng.(2017).Trichalcogenasumanene ortho-Quinones: Synthesis, Properties, and Transformation into Various Heteropolycycles.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(43),13470-13474. |
| MLA | Sun, Yantao,et al."Trichalcogenasumanene ortho-Quinones: Synthesis, Properties, and Transformation into Various Heteropolycycles".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.43(2017):13470-13474. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。