中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Nitrogen-doped hollow carbon spheres derived from amination reaction of fullerene with alkyl diamines as a carbon catalyst for hydrogenation of aromatic nitro compounds

文献类型:期刊论文

作者Sun, Yongbin1,2; Cao, Changyan2; Liu, Chang2; Liu, Jian2; Zhu, Yanan2; Wang, Xiaoshi2; Song, Weiguo2
刊名CARBON
出版日期2017-12-01
卷号125页码:139-145
英文摘要Hollow carbon nanospheres have received much interest by virtue of the special shape, low density and large interior void space, allowing their many potential applications. Here we report a template-free route to produce nitrogen-doped hollow porous carbon spheres (denoted as N-HPCSs) through amination reaction of C-60 with alkyl diamines and subsequent carbonization. The size of wall thickness and cavity of hollow carbon spheres could be easily regulated by the chain length of alkyl diamines. After carbonization in Ar atmosphere, the obtained N-HPCSs exhibited excellent activity and recyclability for hydrogenation of aromatic nitro compounds with hydrazine hydrate. The facile approach presented in this work provides a new way for preparation of doped hollow porous carbon spheres. (C) 2017 Elsevier Ltd. All rights reserved.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/41294]  
专题化学研究所_分子纳米结构与纳米技术实验室
作者单位1.TaiShan Med Univ, Sch Chem & Pharmaceut Engn, Tai An 271000, Shandong, Peoples R China
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Lab Mol Nanostruct & Nanotechnol, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Sun, Yongbin,Cao, Changyan,Liu, Chang,et al. Nitrogen-doped hollow carbon spheres derived from amination reaction of fullerene with alkyl diamines as a carbon catalyst for hydrogenation of aromatic nitro compounds[J]. CARBON,2017,125:139-145.
APA Sun, Yongbin.,Cao, Changyan.,Liu, Chang.,Liu, Jian.,Zhu, Yanan.,...&Song, Weiguo.(2017).Nitrogen-doped hollow carbon spheres derived from amination reaction of fullerene with alkyl diamines as a carbon catalyst for hydrogenation of aromatic nitro compounds.CARBON,125,139-145.
MLA Sun, Yongbin,et al."Nitrogen-doped hollow carbon spheres derived from amination reaction of fullerene with alkyl diamines as a carbon catalyst for hydrogenation of aromatic nitro compounds".CARBON 125(2017):139-145.

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来源:化学研究所

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