A new type of copper coordination polymer based on gamma-aminobutyric acid: Syntheses, structures and magnetic properties
文献类型：期刊论文
| 作者 | Si, Wen1; Qiu, Qi-ming1; Liu, Cai-ming2; Kou, Hui-zhong3; Dong, Lu1; Wang, Wenjie1; Li, Hui1 |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2017-10-01 |
| 卷号 | 84页码:99-102 |
| 关键词 | Coordination Polymer Gamma-aminobutyric Acid Magnetic Property Coupling |
| 英文摘要 | A copper coordination polymer with gamma-aminobutyric acid (GABA), {[Cu-3(GABA)(2)(NO3)(2)(OH)(2)(H2O)(2)] (NO3)(2)center dot 2H(2)O}(n) (1), has been synthesized and characterized by single-crystal X-ray diffraction, IR, PXRD, TGA and elemental analysis. It exhibits a 1D chain structure including mu(3)-OH-Cu-3 cluster as a building block. The strong H-bonding links these chains to form 2D sheet structure and the main intermolecular interaction between the 2D sheets is electrostatic interaction. According to the crystal structure of complex 1, the magnetic properties of complex 1 have been investigated by the cluster and cycle magnetic coupling models. There are three different magnetic coupling pathways of Cu(II) (J(1), J(2), J(3)) from each method and the resulting fitted curves based on the magnetic parameters of both methods compare well with the experiment values. (C) 2017 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41307]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Beijing Inst Technol, Sch Chem & Chem Engn, Key Lab Clusters Sci, Minist Educ, Beijing 100081, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Si, Wen,Qiu, Qi-ming,Liu, Cai-ming,et al. A new type of copper coordination polymer based on gamma-aminobutyric acid: Syntheses, structures and magnetic properties[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2017,84:99-102. |
| APA | Si, Wen.,Qiu, Qi-ming.,Liu, Cai-ming.,Kou, Hui-zhong.,Dong, Lu.,...&Li, Hui.(2017).A new type of copper coordination polymer based on gamma-aminobutyric acid: Syntheses, structures and magnetic properties.INORGANIC CHEMISTRY COMMUNICATIONS,84,99-102. |
| MLA | Si, Wen,et al."A new type of copper coordination polymer based on gamma-aminobutyric acid: Syntheses, structures and magnetic properties".INORGANIC CHEMISTRY COMMUNICATIONS 84(2017):99-102. |
入库方式： OAI收割
来源：化学研究所
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