Iodide/tert-Butyl Hydroperoxide-Mediated Benzylic C-H Sulfonylation and Peroxidation of Phenol Derivatives
文献类型：期刊论文
| 作者 | Yang, Wen-Chao1,2,3; Dai, Peng1,2; Luo, Kai1,2,3; Wu, Lei1,2,4,5 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2016-10-20 |
| 卷号 | 358期号:20页码:3184-3190 |
| 关键词 | Benzylic C-h Functionalization Metal-free Conditions Peroxidation Phenol Derivatives Sulfonylation |
| 英文摘要 | We disclose here the first iodine/tert-butyl hydroperoxide (I-2/TBHP)-mediated benzylic C-H sulfonylation of phenol derivatives. This new methodology provides an economic, operationally simple and metal-free approach toward C(sp(3))-S bond formation with medium to excellent yields at room temperature. Moreover, a novel sulfonylative and peroxidative bifunctionalization of phenol derivatives was also achieved by changing the amount of the oxidant. The reaction mechanism is exemplified via a radical pathway. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/37979]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Nanjing Agr Univ, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China 2.Nanjing Agr Univ, Dept Chem, Coll Sci, Nanjing 210095, Jiangsu, Peoples R China 3.Nanjing Agr Univ, Coll Plant Protect, Nanjing 210095, Jiangsu, Peoples R China 4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Wen-Chao,Dai, Peng,Luo, Kai,et al. Iodide/tert-Butyl Hydroperoxide-Mediated Benzylic C-H Sulfonylation and Peroxidation of Phenol Derivatives[J]. ADVANCED SYNTHESIS & CATALYSIS,2016,358(20):3184-3190. |
| APA | Yang, Wen-Chao,Dai, Peng,Luo, Kai,&Wu, Lei.(2016).Iodide/tert-Butyl Hydroperoxide-Mediated Benzylic C-H Sulfonylation and Peroxidation of Phenol Derivatives.ADVANCED SYNTHESIS & CATALYSIS,358(20),3184-3190. |
| MLA | Yang, Wen-Chao,et al."Iodide/tert-Butyl Hydroperoxide-Mediated Benzylic C-H Sulfonylation and Peroxidation of Phenol Derivatives".ADVANCED SYNTHESIS & CATALYSIS 358.20(2016):3184-3190. |
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来源：化学研究所
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