Efficient Hydrogenation of Nitrogen Heterocycles Catalyzed by Carbon-Metal Covalent Bonds-Stabilized Palladium Nanoparticles: Synergistic Effects of Particle Size and Water
文献类型：期刊论文
| 作者 | Zhang, Yu1,2; Zhu, Jie1,2; Xia, Yun-Tao1,2; Sun, Xiao-Tao1,2; Wu, Lei1,2,3,4 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2016-10-06 |
| 卷号 | 358期号:19页码:3039-3045 |
| 关键词 | Carbon-metal Covalent Bonds Catalytic Hydrogenation Nitrogen Heterocycles Stabilized Palladium Nanoparticles Synergistic Effects |
| 英文摘要 | We reveal here the first hydrogenation of nitrogen heterocycles catalyzed by carbon-metal covalent bonds-stabilized palladium nanoparticles in water under mild conditions. Using a one-phase reduction method, smaller metal-carbon covalent bond-stabilized Pd nanoparticles were prepared with a size distribution of 2.5 +/- 0.5 nm, which showed extraordinary synergistic effects with water in the catalytic hydrogenation of nitrogen heterocycles. Water was supposed to accelerate substrate absorption and synergistic activation of molecular hydrogen on the Pd nanoparticles surface. The nanosized Pd catalyst could be easily recovered and reused for 5 runs. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38004]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Nanjing Agr Univ, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China 2.Nanjing Agr Univ, Coll Sci, Dept Chem, Nanjing 210095, Jiangsu, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yu,Zhu, Jie,Xia, Yun-Tao,et al. Efficient Hydrogenation of Nitrogen Heterocycles Catalyzed by Carbon-Metal Covalent Bonds-Stabilized Palladium Nanoparticles: Synergistic Effects of Particle Size and Water[J]. ADVANCED SYNTHESIS & CATALYSIS,2016,358(19):3039-3045. |
| APA | Zhang, Yu,Zhu, Jie,Xia, Yun-Tao,Sun, Xiao-Tao,&Wu, Lei.(2016).Efficient Hydrogenation of Nitrogen Heterocycles Catalyzed by Carbon-Metal Covalent Bonds-Stabilized Palladium Nanoparticles: Synergistic Effects of Particle Size and Water.ADVANCED SYNTHESIS & CATALYSIS,358(19),3039-3045. |
| MLA | Zhang, Yu,et al."Efficient Hydrogenation of Nitrogen Heterocycles Catalyzed by Carbon-Metal Covalent Bonds-Stabilized Palladium Nanoparticles: Synergistic Effects of Particle Size and Water".ADVANCED SYNTHESIS & CATALYSIS 358.19(2016):3039-3045. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。