Controlling Helix Sense at N- and C-Termini in Quinoline Oligoamide Foldamers by beta-Pinene-Derived Pyridyl Moieties
文献类型：期刊论文
| 作者 | Zheng, Lu1; Zhan, Yulin1; Yu, Chengyuan1; Huang, Fu1,2; Wang, Ying1; Jiang, Hua1 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2017-03-17 |
| 卷号 | 19期号:6页码:1482-1485 |
| 英文摘要 | A series of quinoline oligoamide foldamers bearing a beta-pinene-derived pyridyl group at the N-terminus or the C terminus were synthesized, and the efficiencies of chiral inductions have been evaluated by H-1 NMR and CD spectra. The chiral inductions were quantitative when chiral pyridyl acid was appended at the N-terminus, but were inferior when chiral pyridyl amine was appended at the C-terminus. Unexpectedly, N-oxidation on the pyridine ring at the C-terminus does not notably enhance the chiral induction efficiency in spite of the presence of three-center hydrogen bonds. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38282]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Beijing Normal Univ, Coll Chem, Key Lab Radiopharmaceut, Key Lab Theoret & Computat Photochem, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Lu,Zhan, Yulin,Yu, Chengyuan,et al. Controlling Helix Sense at N- and C-Termini in Quinoline Oligoamide Foldamers by beta-Pinene-Derived Pyridyl Moieties[J]. ORGANIC LETTERS,2017,19(6):1482-1485. |
| APA | Zheng, Lu,Zhan, Yulin,Yu, Chengyuan,Huang, Fu,Wang, Ying,&Jiang, Hua.(2017).Controlling Helix Sense at N- and C-Termini in Quinoline Oligoamide Foldamers by beta-Pinene-Derived Pyridyl Moieties.ORGANIC LETTERS,19(6),1482-1485. |
| MLA | Zheng, Lu,et al."Controlling Helix Sense at N- and C-Termini in Quinoline Oligoamide Foldamers by beta-Pinene-Derived Pyridyl Moieties".ORGANIC LETTERS 19.6(2017):1482-1485. |
入库方式： OAI收割
来源：化学研究所
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