Enhance photovoltaic performance of tris(2,2'-bipyridine) cobalt(II)/(III) based dye-sensitized solar cells via modifying TiO2 surface with metal organic frameworks
文献类型：期刊论文
| 作者 | Gu, Anna1; Xiang, Wanchun1; Wang, Taishan2; Gu, Shaoxuan1; Zhao, Xiujian1 |
| 刊名 | SOLAR ENERGY
 |
| 出版日期 | 2017-05-01 |
| 卷号 | 147页码:126-132 |
| 关键词 | Dye-sensitized Solar Cells Metal Organic Frameworks Cobalt Trisbipyridine |
| 英文摘要 | A very thin blocking layer of a metal organic framework ZIF-8 has been successfully coated on the surface of mesoporous TiO2 films. Compared to the uncoated samples, dye-sensitized solar cells with such films exhibit enhanced open circuit voltage (V-oc) and short circuit current (Jsc) by 3% and 21%, respectively, leading to a 9.42% energy conversion efficiency using tris(2,2'-bipyridine) cobalt(II)/(III) redox mediator. The electron lifetimes as well as dye loading on TiO2 working electrodes were found to increase after ZIF-8 treatment, which is responsible for the improvement of Jsc. An increase of charge recombination resistance between working electrode and organic electrolyte, as is characterized by electrochemical impedance spectra, is proposed to be the reason for the increased Voc, as there is no TiO2 conduction band shift after the treatment of ZIF-8. (C) 2017 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38372]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Wuhan Univ Technol, State Key Lab Silicate Mat Architecture, Luoshi Rd, Wuhan 430070, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Beijing Mol Sci Natl Lab, Zhongguancunbeiyijie 2 Hao, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gu, Anna,Xiang, Wanchun,Wang, Taishan,et al. Enhance photovoltaic performance of tris(2,2'-bipyridine) cobalt(II)/(III) based dye-sensitized solar cells via modifying TiO2 surface with metal organic frameworks[J]. SOLAR ENERGY,2017,147:126-132. |
| APA | Gu, Anna,Xiang, Wanchun,Wang, Taishan,Gu, Shaoxuan,&Zhao, Xiujian.(2017).Enhance photovoltaic performance of tris(2,2'-bipyridine) cobalt(II)/(III) based dye-sensitized solar cells via modifying TiO2 surface with metal organic frameworks.SOLAR ENERGY,147,126-132. |
| MLA | Gu, Anna,et al."Enhance photovoltaic performance of tris(2,2'-bipyridine) cobalt(II)/(III) based dye-sensitized solar cells via modifying TiO2 surface with metal organic frameworks".SOLAR ENERGY 147(2017):126-132. |
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来源：化学研究所
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