Tunable photoluminescence from layered rare-earth hydroxide/polymer nanocomposite hydrogels by a cascaded energy transfer effect
文献类型：期刊论文
| 作者 | Wu, Lianying1,3; Gao, Caiyan1; Li, Zhibo2; Chen, Guangming1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2017-06-07 |
| 卷号 | 5期号:21页码:5207-5213 |
| 英文摘要 | Polymer/inorganic nanocomposite (NC) hydrogels usually display super mechanical properties, due to their 3D crosslinked network of delaminated inorganic nanoparticles and polymers as well as strong interfacial interactions. Multiple functions including photoluminescence are strongly desired for their applications. In this study, we report layered rare-earth hydroxide (LRH)/polyacrylamide NC hydrogels with highly colour-tunable photoluminescence functions by a cascaded energy transfer effect. These NC hydrogels based on LRHs containing Gd3+, Tb3+ or Eu3+ ions are fabricated via a convenient and green in situ polymerization procedure. Diverse photoluminescent colours are clearly observed, ranging from green, yellow-green, yellow, reddish-orange, yellowish pink, pink to bluish violet. Furthermore, these NC hydrogels exhibit long luminescence lifetimes and high quantum efficiencies. More interestingly, such fascinating photoluminescence features are highly tunable by varying the constituent or concentration of LRHs, and the excitation wavelength. Finally, a cascaded energy transfer pathway is proposed to elucidate the molecular mechanism of the tunable multiple-colour photoluminescence functions, i.e. the LRH host -> sensitizer sodium salicylate (SA) -> Tb3+, and finally Tb3+ -> Eu3+. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38529]  |
| 专题 | 化学研究所_绿色印刷实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 2.Qingdao Univ Sci & Technol, Sch Polymer Sci & Engn, Qingdao 266042, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Lianying,Gao, Caiyan,Li, Zhibo,et al. Tunable photoluminescence from layered rare-earth hydroxide/polymer nanocomposite hydrogels by a cascaded energy transfer effect[J]. JOURNAL OF MATERIALS CHEMISTRY C,2017,5(21):5207-5213. |
| APA | Wu, Lianying,Gao, Caiyan,Li, Zhibo,&Chen, Guangming.(2017).Tunable photoluminescence from layered rare-earth hydroxide/polymer nanocomposite hydrogels by a cascaded energy transfer effect.JOURNAL OF MATERIALS CHEMISTRY C,5(21),5207-5213. |
| MLA | Wu, Lianying,et al."Tunable photoluminescence from layered rare-earth hydroxide/polymer nanocomposite hydrogels by a cascaded energy transfer effect".JOURNAL OF MATERIALS CHEMISTRY C 5.21(2017):5207-5213. |
入库方式： OAI收割
来源：化学研究所
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