Room temperature processed polymers for high-efficient polymer solar cells with power conversion efficiency over 9%
文献类型：期刊论文
| 作者 | Liao, Xunfan1,2; Zhang, Lin3; Chen, Lie1,2; Hu, Xiaotian4; Ai, Qingyun1; Ma, Wei3; Chen, Yiwang1,2 |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2017-07-01 |
| 卷号 | 37页码:32-39 |
| 关键词 | Room Temperature Processing Organic Solar Cells Temperature-dependent Aggregation Domain Purity Random Polymerization |
| 英文摘要 | Although the family of difluoro-2,1,3-benzothiadiazole with 2-octyldodecyl alkyl chains based donor copolymers have reached over 10% power conversion efficiencies (PCE) in past three years, several limitations are holding back their further commercialization application. For instance, those polymers have to be processed at a high temperature (similar to 110 degrees C) due to their strong aggregation in the solution. Here we report the achievement of low temperature-processed polymers for high-efficient polymer solar cells (PSCs) via random polymerization. The introduction of 2,2'-(perfluoro-1,4-phenylene)dithiophene (2TPF4) via random polymerization can weaken the strong self-aggregation of the polymers, enabling the polymers processible by spin-coating at room temperature as well as favor the formation of a near ideal active layer morphology which involves highly crystalline yet with reasonably small polymer domains. All these three polymers exhibit preferable face-on orientation and the domain purity could be significantly changed by the introduction of 2TPF4 block. A superior PCE of 9.4% of the photovoltaic device based on PffBT-2TPF4-9/1 was obtained, which is one of the best values for room temperature-processed solar cells. These findings indicate that low temperature processed high-efficient PSCs can be achieved by rational conjugated backbone engineering, which presents distinctive advantages for largescale production in the near future. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38541]  |
| 专题 | 化学研究所_绿色印刷实验室 |
| 作者单位 | 1.Nanchang Univ, Coll Chem, 999 Xuefu Ave, Nanchang 330031, Jiangxi, Peoples R China 2.Nanchang Univ, Inst Polymers, Jiangxi Prov Key Lab New Energy Chem, 999 Xuefu Ave, Nanchang 330031, Jiangxi, Peoples R China 3.Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China 4.Chinese Acad Sci ICCAS, Inst Chem, Key Lab Green Printing, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liao, Xunfan,Zhang, Lin,Chen, Lie,et al. Room temperature processed polymers for high-efficient polymer solar cells with power conversion efficiency over 9%[J]. NANO ENERGY,2017,37:32-39. |
| APA | Liao, Xunfan.,Zhang, Lin.,Chen, Lie.,Hu, Xiaotian.,Ai, Qingyun.,...&Chen, Yiwang.(2017).Room temperature processed polymers for high-efficient polymer solar cells with power conversion efficiency over 9%.NANO ENERGY,37,32-39. |
| MLA | Liao, Xunfan,et al."Room temperature processed polymers for high-efficient polymer solar cells with power conversion efficiency over 9%".NANO ENERGY 37(2017):32-39. |
入库方式： OAI收割
来源：化学研究所
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