Formation of Nitrogen-Doped Mesoporous Graphitic Carbon with the Help of Melamine
文献类型：期刊论文
| 作者 | Li, Ruimin; Cao, Anmin; Zhang, Yanjun; Li, Gen; Jiang, Feng; Li, Shumu; Chen, Daiqin; Wang, Chunru; Ge, Jiechao; Shu, Chunying |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | DEC 20 2014 |
| 卷号 | 6期号:23页码:20574-20578 |
| 英文摘要 | Sulfur, trace nitrogen and iron codoped, hierarchically porous carbon foams (HPCFs) were fabricated by directly pyrolyzing sulfur-enriched conductive polymer, poly(3,4-ethylenedioxythiphene)-polystyrenesulfonic acid (PEDOT-PSS) aerogels under argon atmosphere. This simple pyrolysis treatment results in the molecular rearrangement of heteroatom sulfur, adjacent carbons and trace nitrogen/iron from oxidants to form active catalytic sites of HPCFs. At the same time, the high porosity of HPCFs provides the large surface area for the uniform distribution of active sites, and allows rapid oxygen transport and diffusion. As a result, these HPCFs exhibit the enhanced catalytic performances for oxygen reduction reaction (ORR) via a direct four-electron reduction pathway in alkaline electrolyte. Besides, they also display a higher stability and better methanol/CO tolerance than the commercial Pt/C catalyst, which makes them promising low cost, non-precious-metal ORR catalysts for practical application in fuel cells and metal-air batteries. |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38571]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Li, Ruimin,Cao, Anmin,Zhang, Yanjun,et al. Formation of Nitrogen-Doped Mesoporous Graphitic Carbon with the Help of Melamine[J]. ACS APPLIED MATERIALS & INTERFACES,DEC ,6(23):20574-20578. |
| APA | Li, Ruimin.,Cao, Anmin.,Zhang, Yanjun.,Li, Gen.,Jiang, Feng.,...&Shu, Chunying.(DEC ).Formation of Nitrogen-Doped Mesoporous Graphitic Carbon with the Help of Melamine.ACS APPLIED MATERIALS & INTERFACES,6(23),20574-20578. |
| MLA | Li, Ruimin,et al."Formation of Nitrogen-Doped Mesoporous Graphitic Carbon with the Help of Melamine".ACS APPLIED MATERIALS & INTERFACES 6.23(DEC ):20574-20578. |
入库方式： OAI收割
来源：化学研究所
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