Stereocontrolled Synthesis of Benzo[k]fluoranthenes-An Unexpected Isomerization Mediated by Rhodacyclopentadiene
文献类型：期刊论文
| 作者 | Xu, Shengjie; Chen, Kejuan; Chen, Hui; Yao, Jiannian; Zhu, Xiaozhang |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | DEC 8 2014 |
| 卷号 | 20期号:50页码:16442-16447 |
| 英文摘要 | A new kind of podand-based dimeric salen ligand was synthesized, and its association with potassium cations was investigated by H-1 NMR spectroscopy. The corresponding Cr-III-salen dimer was assembled by a supramolecular host-guest self-assembly process and was then used as a catalyst in highly efficient and enantioselective asymmetric Henry reactions. Regulation by KBArF (BArF = [3,5-(CF3)(2)C6H3](4)B) led to remarkable improvements in yield (by up to 58%) and enantioselectivity (for example, from 80% ee to 96% ee). |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38587]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Xu, Shengjie,Chen, Kejuan,Chen, Hui,et al. Stereocontrolled Synthesis of Benzo[k]fluoranthenes-An Unexpected Isomerization Mediated by Rhodacyclopentadiene[J]. CHEMISTRY-A EUROPEAN JOURNAL,DEC ,20(50):16442-16447. |
| APA | Xu, Shengjie,Chen, Kejuan,Chen, Hui,Yao, Jiannian,&Zhu, Xiaozhang.(DEC ).Stereocontrolled Synthesis of Benzo[k]fluoranthenes-An Unexpected Isomerization Mediated by Rhodacyclopentadiene.CHEMISTRY-A EUROPEAN JOURNAL,20(50),16442-16447. |
| MLA | Xu, Shengjie,et al."Stereocontrolled Synthesis of Benzo[k]fluoranthenes-An Unexpected Isomerization Mediated by Rhodacyclopentadiene".CHEMISTRY-A EUROPEAN JOURNAL 20.50(DEC ):16442-16447. |
入库方式： OAI收割
来源：化学研究所
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