A bioinspired approach to protectively decorate platinum-carbon for enhanced activity and durability in oxygen reduction
文献类型：期刊论文
| 作者 | Huang, Yiyin; Fu, Fang; Wu, Peng; Wang, Yaobing; Yao, Jiannian |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | DEC 5 2014 |
| 卷号 | 268页码:591-595 |
| 英文摘要 | Electronic delocalization effects have been proposed to play a key role in photocurrent generation in organic photovoltaic devices. Here, we study the role of charge delocalization on the nature of the charge-transfer (CT) states in the case of model complexes consisting of several pentacene molecules and one fullerene (C-60) molecule, which are representative of donor/acceptor heterojunctions. The energies of the CT states are examined by means of time-dependent density functional theory (TD-DFT) using the long-range-corrected functional, pi B97X, with an optimized range-separation parameter, ?. We provide a general description of how the nature of the CT states is impacted by molecular packing (i.e., interfacial donor/acceptor orientations), system size, and intermolecular interactions, features of importance in the understanding of the charge-separation mechanism. |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38590]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Huang, Yiyin,Fu, Fang,Wu, Peng,et al. A bioinspired approach to protectively decorate platinum-carbon for enhanced activity and durability in oxygen reduction[J]. JOURNAL OF POWER SOURCES,DEC ,268:591-595. |
| APA | Huang, Yiyin,Fu, Fang,Wu, Peng,Wang, Yaobing,&Yao, Jiannian.(DEC ).A bioinspired approach to protectively decorate platinum-carbon for enhanced activity and durability in oxygen reduction.JOURNAL OF POWER SOURCES,268,591-595. |
| MLA | Huang, Yiyin,et al."A bioinspired approach to protectively decorate platinum-carbon for enhanced activity and durability in oxygen reduction".JOURNAL OF POWER SOURCES 268(DEC ):591-595. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。