Outgassing analysis of molecular glass photoresists under EUV irradiation
文献类型：期刊论文
| 作者 | Chen Li; Xu Jian; Yuan Hua; Yang ShuMin; Wang LianSheng; Wu YanQing; Zhao Jun; Chen Ming; Liu HaiGang; Li ShaYu |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2014-12-01 |
| 卷号 | 57期号:12页码:1746-1750 |
| 英文摘要 | By a one-pot reaction strategy and a stepwise fragment-coupling approach, three types of giant cage molecules with a triangular prism shape and an approximate cavity volume of 930 angstrom(3) were synthesized. Through efficient aromatic nucleophilic substitution reactions of chlorotriazine with functionalized amines or aliphatic substitution reactions of the linking imino moieties with allyl bromide, the giant cages were successfully functionalized on the surface with multiple hydroxy, 2-pyridyl, or allyl groups. As evidenced by variable-temperature H-1 NMR spectroscopy, the D-3h- and C-3v-symmetric cage molecules underwent very slow conformational changes or deformation in solution because of their giant size and their flexible building units. Their giant cavities, different electronic interiors, and facile multiple exterior surface functionalization could render the molecular cages powerful three-dimensional macrocyclic hosts that might find wide applications in supramolecular science. |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38606]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Chen Li,Xu Jian,Yuan Hua,et al. Outgassing analysis of molecular glass photoresists under EUV irradiation[J]. SCIENCE CHINA-CHEMISTRY,2014,57(12):1746-1750. |
| APA | Chen Li.,Xu Jian.,Yuan Hua.,Yang ShuMin.,Wang LianSheng.,...&Yang GuoQiang.(2014).Outgassing analysis of molecular glass photoresists under EUV irradiation.SCIENCE CHINA-CHEMISTRY,57(12),1746-1750. |
| MLA | Chen Li,et al."Outgassing analysis of molecular glass photoresists under EUV irradiation".SCIENCE CHINA-CHEMISTRY 57.12(2014):1746-1750. |
入库方式： OAI收割
来源：化学研究所
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