Two-Dimensional pi-Expanded Quinoidal Terthiophenes Terminated with Dicyanomethylenes as n-Type Semiconductors for High-Performance Organic Thin-Film Transistors
文献类型：期刊论文
| 作者 | Zhang, Cheng; Zang, Yaping; Gann, Eliot; McNeill, Christopher R.; Zhu, Xiaozhang; Di, Chong-an; Zhu, Daoben |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | NOV 19 2014 |
| 卷号 | 136期号:46页码:16176-16184 |
| 英文摘要 | Poly(ethylene oxide)-block-poly(2-(diethylamino)ethyl methacrylate) (PEO-b-PDEAEMA) diblock copolymer was synthesized by anionic polymerization, whose molecular structure was characterized by H-1 NMR and size exclusion chromatography (SEC). The diblock copolymer self-assembled into micelles in nonacid aqueous solution with PEO and PDEAEMA as corona and core respectively. By virtue of the coordinating property of PDEAEMA block to metal ions, the resultant micelles were then used as carriers to load metal ions Y(III) and Cu(II) in the micellar core. The morphology and stability of the metal loaded micelles were characterized by dynamic light scattering (DLS), atomic force microscopy (AFM) and transmission electron microscopy (TEM). The metal loading amounts were determined by elemental analyses, UV spectrometry and titrimetric analysis. In addition, the Y(III) loaded micelles were demonstrated to complex with alpha-cyclodextrins and form supramolecular hydrogels in-situ. The metal loaded micelles and the resultant supramolecular hydrogels will have potential application for cancer internal radiotherapy. (C) 2014 Elsevier Ltd. All rights reserved. |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38632]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Zhang, Cheng,Zang, Yaping,Gann, Eliot,et al. Two-Dimensional pi-Expanded Quinoidal Terthiophenes Terminated with Dicyanomethylenes as n-Type Semiconductors for High-Performance Organic Thin-Film Transistors[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,NOV ,136(46):16176-16184. |
| APA | Zhang, Cheng.,Zang, Yaping.,Gann, Eliot.,McNeill, Christopher R..,Zhu, Xiaozhang.,...&Zhu, Daoben.(NOV ).Two-Dimensional pi-Expanded Quinoidal Terthiophenes Terminated with Dicyanomethylenes as n-Type Semiconductors for High-Performance Organic Thin-Film Transistors.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,136(46),16176-16184. |
| MLA | Zhang, Cheng,et al."Two-Dimensional pi-Expanded Quinoidal Terthiophenes Terminated with Dicyanomethylenes as n-Type Semiconductors for High-Performance Organic Thin-Film Transistors".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136.46(NOV ):16176-16184. |
入库方式： OAI收割
来源：化学研究所
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