Interface Design to Improve the Performance and Stability of Solution-Processed Small-Molecule Conventional Solar Cells
文献类型：期刊论文
| 作者 | Min, Jie; Luponosov, Yuriy N.; Zhang, Zhi-Guo; Ponomarenko, Sergei A.; Ameri, Tayebeh; Li, Yongfang; Brabec, Christoph J. |
| 刊名 | ADVANCED ENERGY MATERIALS
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| 出版日期 | NOV 18 2014 |
| 卷号 | 4期号:16 |
| 英文摘要 | Aggregation-induced emission (AIE) has been harnessed in many systems through the principle of restriction of intramolecular rotations (RIR) based on mechanistic understanding from archetypal AIE molecules such as tetraphenylethene (TPE). However, as the family of AIE-active molecules grows, the RIR model cannot fully explain some AIE phenomena. Here, we report a broadening of the AIE mechanism through analysis of 10,10',11,11'-tetrahydro-5,5'-bidibenzo[a,d][7]annulenylidene (THBDBA), and 5,5'-bidibenzo[a, d][7] annulenylidene (BDBA). Analyses of the computational QM/MM model reveal that the novel mechanism behind the AIE of THBDBA and BDBA is the restriction of intramolecular vibration (RIV). A more generalized mechanistic understanding of AIE results by combining RIR and RIV into the principle of restriction of intramolecular motions (RIM). |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38633]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Min, Jie,Luponosov, Yuriy N.,Zhang, Zhi-Guo,et al. Interface Design to Improve the Performance and Stability of Solution-Processed Small-Molecule Conventional Solar Cells[J]. ADVANCED ENERGY MATERIALS,NOV ,4(16). |
| APA | Min, Jie.,Luponosov, Yuriy N..,Zhang, Zhi-Guo.,Ponomarenko, Sergei A..,Ameri, Tayebeh.,...&Brabec, Christoph J..(NOV ).Interface Design to Improve the Performance and Stability of Solution-Processed Small-Molecule Conventional Solar Cells.ADVANCED ENERGY MATERIALS,4(16). |
| MLA | Min, Jie,et al."Interface Design to Improve the Performance and Stability of Solution-Processed Small-Molecule Conventional Solar Cells".ADVANCED ENERGY MATERIALS 4.16(NOV ). |
入库方式： OAI收割
来源：化学研究所
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