中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Photoacoustic Imaging Guided Near-Infrared Photothermal Therapy Using Highly Water-Dispersible Single-Walled Carbon Nanohorns as Theranostic Agents

文献类型:期刊论文

作者Chen, Daiqin; Wang, Chao; Nie, Xin; Li, Shumu; Li, Ruimin; Guan, Mirong; Liu, Zhuang; Chen, Chunying; Wang, Chunru; Shu, Chunying
刊名ADVANCED FUNCTIONAL MATERIALS
出版日期NOV 12 2014
卷号24期号:42页码:6621-6628
英文摘要Adding a small amount of a processing additive to the casting solution of photoactive organic blends has been demonstrated to be an effective method for achieving improved power conversion efficiency (PCE) in organic photovoltaics (OPVs). However, an understanding of the nano-structural evolution occurring in the transformation from casting solution to thin photoactive films is still lacking. In this report, the effects of the processing additive diiodooctane (DIO) on the morphology of the established blend of PBDTTT-C-T polymer and the fullerene derivative PC71BM used for OPVs are investigated, starting in the casting solution and tracing the effects in spun-cast thin films by using neutron/X-ray scattering, neutron reflectometry, and other characterization techniques. The results reveal that DIO has no observable effect on the structures of PBDTTT-C-T and PC71BM in solution; however, in the spun-cast films, it significantly promotes their molecular ordering and phase segregation, resulting in improved PCE. Thermodynamic analysis based on Flory-Huggins theory provides a rationale for the effects of DIO on different characteristics of phase segregation due to changes in concentration resulting from evaporation of the solvent and additive during film formation. Such information may help improve the rational design of ternary blends to more consistently achieve improved PCE for OPVs.
源URL[http://ir.iccas.ac.cn/handle/121111/38638]  
专题化学研究所_其它
推荐引用方式
GB/T 7714
Chen, Daiqin,Wang, Chao,Nie, Xin,et al. Photoacoustic Imaging Guided Near-Infrared Photothermal Therapy Using Highly Water-Dispersible Single-Walled Carbon Nanohorns as Theranostic Agents[J]. ADVANCED FUNCTIONAL MATERIALS,NOV ,24(42):6621-6628.
APA Chen, Daiqin.,Wang, Chao.,Nie, Xin.,Li, Shumu.,Li, Ruimin.,...&Wan, Lijun.(NOV ).Photoacoustic Imaging Guided Near-Infrared Photothermal Therapy Using Highly Water-Dispersible Single-Walled Carbon Nanohorns as Theranostic Agents.ADVANCED FUNCTIONAL MATERIALS,24(42),6621-6628.
MLA Chen, Daiqin,et al."Photoacoustic Imaging Guided Near-Infrared Photothermal Therapy Using Highly Water-Dispersible Single-Walled Carbon Nanohorns as Theranostic Agents".ADVANCED FUNCTIONAL MATERIALS 24.42(NOV ):6621-6628.

入库方式: OAI收割

来源:化学研究所

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