Alanine-Based Chiral Metallogels via Supramolecular Coordination Complex Platforms: Metallogelation Induced Chirality Transfer
文献类型：期刊论文
| 作者 | Sun, Yue; Li, Shuai; Zhou, Zhixuan; Saha, Manik Lal; Datta, Sougata; Zhang, Mingming; Yang, Xuzhou; Tian, Demei; Wang, Heng; Wang, Lei |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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| 出版日期 | MAR 7 2018 |
| 卷号 | 140期号:9页码:3257-3263 |
| 英文摘要 | Chiral self-assemblies constantly attract great interest because of their potential to provide insight into biological systems and materials science. Herein we report on the efficient preparation of alanine-based chiral metallacycles, rhomboids 1(D) and 1(L) and hexagons 2(D) and 2(L) using a Pt(II) <- pyridyl directional bonding approach. The metallacycles are subsequently assembled into nanospheres at low concentration, that generate chiral metallogels at high concentration driven by hydrogen bonding, hydrophobic and pi-pi interactions. The gels consist of microscopic chiral nanofibers with well-defined helicity, as confirmed by circular dichroism (CD) and scanning (SEM) and transmission electron (TEM) microscopies. Given these results, we expect this technique will not only unlock interesting new approaches to understand homochirality in nature but also allow the design of versatile soft materials containing chiral supramolecular cores. |
| WOS记录号 | WOS:000427203600018 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38717]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Sun, Yue,Li, Shuai,Zhou, Zhixuan,et al. Alanine-Based Chiral Metallogels via Supramolecular Coordination Complex Platforms: Metallogelation Induced Chirality Transfer[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,MAR ,140(9):3257-3263. |
| APA | Sun, Yue.,Li, Shuai.,Zhou, Zhixuan.,Saha, Manik Lal.,Datta, Sougata.,...&Stang, Peter J..(MAR ).Alanine-Based Chiral Metallogels via Supramolecular Coordination Complex Platforms: Metallogelation Induced Chirality Transfer.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,140(9),3257-3263. |
| MLA | Sun, Yue,et al."Alanine-Based Chiral Metallogels via Supramolecular Coordination Complex Platforms: Metallogelation Induced Chirality Transfer".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140.9(MAR ):3257-3263. |
入库方式： OAI收割
来源：化学研究所
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