Mixing O-Containing and N-Containing Directing Groups for C-H Activation: A Strategy for the Synthesis of Highly Functionalized 2,2 '-Biaryls
文献类型：期刊论文
| 作者 | Zhang, Chao; Song, Yugang; Sang, Zhihui; Zhan, Lingpeng; Rao, Yu |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | MAR 2 2018 |
| 卷号 | 83期号:5页码:2582-2591 |
| 英文摘要 | A strategy combining O- and N-containing directing groups has been developed for the synthesis of 2,2'-biaryl via Pd-mediated C-H bond activation and oxidative coupling. This new transformation may proceed through a mechanism involving Pd(II) and Pd(IV) intermediates. We found the use of PTSA and HFIP to be critical for the reaction and suggest that these reagents could serve as efficient ligands for this C-C bond formation. This methodology provides broad functional group tolerance, excellent reactivity, and high yields. |
| WOS记录号 | WOS:000426803300008 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38726]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Zhang, Chao,Song, Yugang,Sang, Zhihui,et al. Mixing O-Containing and N-Containing Directing Groups for C-H Activation: A Strategy for the Synthesis of Highly Functionalized 2,2 '-Biaryls[J]. JOURNAL OF ORGANIC CHEMISTRY,MAR ,83(5):2582-2591. |
| APA | Zhang, Chao,Song, Yugang,Sang, Zhihui,Zhan, Lingpeng,&Rao, Yu.(MAR ).Mixing O-Containing and N-Containing Directing Groups for C-H Activation: A Strategy for the Synthesis of Highly Functionalized 2,2 '-Biaryls.JOURNAL OF ORGANIC CHEMISTRY,83(5),2582-2591. |
| MLA | Zhang, Chao,et al."Mixing O-Containing and N-Containing Directing Groups for C-H Activation: A Strategy for the Synthesis of Highly Functionalized 2,2 '-Biaryls".JOURNAL OF ORGANIC CHEMISTRY 83.5(MAR ):2582-2591. |
入库方式： OAI收割
来源：化学研究所
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