Anisotropic Paramagnetic Properties of Metallofullerene Confined in a Metal-Organic Framework
文献类型：期刊论文
| 作者 | Zhao, Chong; Meng, Haibing; Nie, Mingzhe; Jiang, Li; Wang, Chunru; Wang, Taishan |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | MAR 1 2018 |
| 卷号 | 122期号:8页码:4635-4640 |
| 英文摘要 | Paramagnetic metallofullerenes have a spherical molecular structure and stable unpaired spin protected by a fullerene cage and have potential applications in quantum information processing, etc. For endohedral azafullerene Y-2@C79N, the N atom on the cage endows the molecule with unpaired spin and is proposed to induce the molecule orientation within the MOF pore via host guest interaction. Angular-dependent EPR spectroscopy was employed on the Y-2@C79N subset of MOF-177 complex to detect the anisotropic paramagnetic properties. These results experimentally confirmed the trend of molecule orientation of Y-2@C79N within MOF-177 under certain conditions, which also induces the presence of several conformers of Y-2@C79N. The additional EPR splittings in Y-2@C79N subset of MOF-177 are proposed to originate from partially disordered molecules as well as the N-coupling of Y-2@C79N upon implanting it into the MOF-177 pore. The N defect on the fullerene cage of Y-2@C79N is expected to be utilized as an anchor to build a three-dimensional spin array within MOF matrix. |
| WOS记录号 | WOS:000426802500060 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38732]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Zhao, Chong,Meng, Haibing,Nie, Mingzhe,et al. Anisotropic Paramagnetic Properties of Metallofullerene Confined in a Metal-Organic Framework[J]. JOURNAL OF PHYSICAL CHEMISTRY C,MAR ,122(8):4635-4640. |
| APA | Zhao, Chong,Meng, Haibing,Nie, Mingzhe,Jiang, Li,Wang, Chunru,&Wang, Taishan.(MAR ).Anisotropic Paramagnetic Properties of Metallofullerene Confined in a Metal-Organic Framework.JOURNAL OF PHYSICAL CHEMISTRY C,122(8),4635-4640. |
| MLA | Zhao, Chong,et al."Anisotropic Paramagnetic Properties of Metallofullerene Confined in a Metal-Organic Framework".JOURNAL OF PHYSICAL CHEMISTRY C 122.8(MAR ):4635-4640. |
入库方式： OAI收割
来源：化学研究所
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