Self-terminated activation for high-yield production of N,P-codoped nanoporous carbon as an efficient metal-free electrocatalyst for Zn-air battery
文献类型：期刊论文
| 作者 | Luo, Hao; Jiang, Wen-Jie; Zhang, Yun; Niu, Shuai; Tang, Tang; Huang, Lin-Bo; Chen, Yu-Yun; Wei, Zidong; Hu, Jin-Song |
| 刊名 | CARBON
 |
| 出版日期 | 2018-03-01 |
| 卷号 | 128页码:97-105 |
| 英文摘要 | To enhance the electrocatalytic activity of heteroatom doped carbon for oxygen reduction reaction (ORR), high surface area and favorable porous structure are commonly required for providing sufficient accessible active sites. However, these features usually come with the severe carbon loss during pyrolysis and activation process. Herein, we report a facile self-terminated activation strategy for high-yield production of nitrogen and phosphorus codoped nanoporous carbon (NP-NC) by using potassium phytate as carbonaceous source. The in-situ formed potassium species enable the effective carbon activation to create plenty of nanopores without additional corrosive chemicals while the formation of K4P2O7 properly terminates the activation, resulting in the extremely low weight loss less than 17%. Benefited from the high surface area of 1294 m(2) g(-1) and trimodal nanoporous structure, the resulted N, P-codoped catalyst exhibits superior ORR activity close to Pt/C, high catalytic current density as well as excellent methanol tolerance and durability. Importantly, as cathode catalyst for Zn-air battery, N, P-NC also exhibits current and power densities comparable to the state-of-the art 20% Pt/C. Therefore, such a facile, scalable and high-yield synthesis of N, P-codoped nanoporous carbon materials opens up opportunities for the mass-production of highly efficient cost-effective electrocatalysts for energy applications. (C) 2017 Elsevier Ltd. All rights reserved. |
| WOS记录号 | WOS:000418479900012 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38746]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Luo, Hao,Jiang, Wen-Jie,Zhang, Yun,et al. Self-terminated activation for high-yield production of N,P-codoped nanoporous carbon as an efficient metal-free electrocatalyst for Zn-air battery[J]. CARBON,2018,128:97-105. |
| APA | Luo, Hao.,Jiang, Wen-Jie.,Zhang, Yun.,Niu, Shuai.,Tang, Tang.,...&Hu, Jin-Song.(2018).Self-terminated activation for high-yield production of N,P-codoped nanoporous carbon as an efficient metal-free electrocatalyst for Zn-air battery.CARBON,128,97-105. |
| MLA | Luo, Hao,et al."Self-terminated activation for high-yield production of N,P-codoped nanoporous carbon as an efficient metal-free electrocatalyst for Zn-air battery".CARBON 128(2018):97-105. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。