A Photoinduced Reversible Phase Transition in a Dipeptide Supramolecular Assembly
文献类型:期刊论文
作者 | Li, Xianbao; Fei, Jinbo; Xu, Youqian; Li, Dongxiang; Yuan, Tingting; Li, Guangle; Wang, Chenlei; Li, Junbai |
刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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出版日期 | FEB 12 2018 |
卷号 | 57期号:7页码:1903-1907 |
英文摘要 | Tunable supramolecular assembly has found various applications in biomedicine, molecular catalysis, optoelectronics, and nanofabrication. Unlike traditional covalent conjugation, non-covalent introduction of a photoswitchable moiety enables reversible photomodulation of non-photosensitive dipeptide supramolecular assembly. Under light illumination, a long-lived photoacid generator releases a proton and mediates the dissociation of dipeptide-based organogel, thereby resulting in sol formation. Under darkness, the photoswitchable moiety entraps a proton, resulting in gel regeneration. Furthermore, accompanying the isothermal recycled gel-sol transition in a spatially controlled manner, renewable patterns are spontaneously fabricated. This new concept of light-controlled phase transition of amino acid-based supramolecular assemblies will open up the possibility of wide applications. |
WOS记录号 | WOS:000424212300026 |
源URL | [http://ir.iccas.ac.cn/handle/121111/38785] ![]() |
专题 | 化学研究所_其它 |
推荐引用方式 GB/T 7714 | Li, Xianbao,Fei, Jinbo,Xu, Youqian,et al. A Photoinduced Reversible Phase Transition in a Dipeptide Supramolecular Assembly[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,FEB ,57(7):1903-1907. |
APA | Li, Xianbao.,Fei, Jinbo.,Xu, Youqian.,Li, Dongxiang.,Yuan, Tingting.,...&Li, Junbai.(FEB ).A Photoinduced Reversible Phase Transition in a Dipeptide Supramolecular Assembly.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(7),1903-1907. |
MLA | Li, Xianbao,et al."A Photoinduced Reversible Phase Transition in a Dipeptide Supramolecular Assembly".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.7(FEB ):1903-1907. |
入库方式: OAI收割
来源:化学研究所
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