中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Sensitive Detection of a Nerve-Agent Simulant through Retightening Internanofiber Binding for Fluorescence Enhancement

文献类型:期刊论文

作者Liu, Xiaoling; Gong, Yanjun; Zheng, Yingxuan; Xiong, Wei; Wang, Chen; Wang, Tie; Che, Yanke; Zhao, Jincai
刊名ANALYTICAL CHEMISTRY
出版日期FEB 6 2018
卷号90期号:3页码:1498-1501
英文摘要In this work, we develop fluorescent hierarchical nanofiber bundles 1, which involve the internanofiber hydrogen-bonding interactions, for rapid and sensitive detection of diethyl chlorophosphate (DCP) vapor. First, the internanofiber hydrogen-bonding strength can be weakened by photo excitation, which thereby increases the internanofiber spacing and decreases the fluorescence intensity. Then, when exposed to trace DCP vapor, the strong interactions between DCP and hydroxyl groups on the nanofibers can effectively retighten the nanofibers and enhance the fluorescence as the detection signal. In contrast, the interferences, such as common organic solvents, cannot retighten nanofiber bundles 1 because of the lack of strong interactions with the nanofibers. On the basis of this novel detection mechanism, fluorescence detection of DCP with rapid signal response (ca. 3 s) and high sensitivity (15 ppb) is achieved.
WOS记录号WOS:000424730600008
源URL[http://ir.iccas.ac.cn/handle/121111/38793]  
专题化学研究所_其它
推荐引用方式
GB/T 7714
Liu, Xiaoling,Gong, Yanjun,Zheng, Yingxuan,et al. Sensitive Detection of a Nerve-Agent Simulant through Retightening Internanofiber Binding for Fluorescence Enhancement[J]. ANALYTICAL CHEMISTRY,FEB ,90(3):1498-1501.
APA Liu, Xiaoling.,Gong, Yanjun.,Zheng, Yingxuan.,Xiong, Wei.,Wang, Chen.,...&Zhao, Jincai.(FEB ).Sensitive Detection of a Nerve-Agent Simulant through Retightening Internanofiber Binding for Fluorescence Enhancement.ANALYTICAL CHEMISTRY,90(3),1498-1501.
MLA Liu, Xiaoling,et al."Sensitive Detection of a Nerve-Agent Simulant through Retightening Internanofiber Binding for Fluorescence Enhancement".ANALYTICAL CHEMISTRY 90.3(FEB ):1498-1501.

入库方式: OAI收割

来源:化学研究所

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