Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate: Structure and luminescence properties
文献类型：期刊论文
| 作者 | Ma, Mengjiao; Li, Congcong; Shu, Dengkun; Wang, Chaohua; Xi, Peng |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | FEB 5 2018 |
| 卷号 | 190页码:68-75 |
| 英文摘要 | A photoluminescent terbium (Tb) complex involving a novel benzoic-acid compound with a unique coordinated structure, namely 1,4-bis(carbonylmethyl)terephthalate (BCMT), has been designed and synthesized. The new coordinate structure and energy-transfer mechanism between the ligand and Tb(III) ions were investigated in detail. The results demonstrated that the BCMT-Tb(III) complex shows strong fluorescence intensity (4 x 10(6) a.u.) and long fluorescence lifetime (1.302 ms), owing to the favorable degree of energy matching between the triplet excited level of the ligand and the resonant level of Tb(III) ions. Based on the analysis of three-dimensional luminescence spectra, the as-prepared Tb(III) complex can be effectively excited in the range of 250-310 nm, and it shows high color purity, with a bright green appearance. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000415912500009 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38799]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Ma, Mengjiao,Li, Congcong,Shu, Dengkun,et al. Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate: Structure and luminescence properties[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,FEB ,190:68-75. |
| APA | Ma, Mengjiao,Li, Congcong,Shu, Dengkun,Wang, Chaohua,&Xi, Peng.(FEB ).Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate: Structure and luminescence properties.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,190,68-75. |
| MLA | Ma, Mengjiao,et al."Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate: Structure and luminescence properties".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 190(FEB ):68-75. |
入库方式： OAI收割
来源：化学研究所
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