Polyimide-Based Self-Standing Polymer Electrolyte Membrane for Lithium-Ion Batteries
文献类型：期刊论文
| 作者 | Wang, Ailian; Xu, Hao; Liu, Fulin; Liu, Xu; Wang, Shi; Zhou, Qian; Chen, Jie; Yang, Shiyong; Zhang, Liaoyun |
| 刊名 | ENERGY TECHNOLOGY
 |
| 出版日期 | 2018-02-01 |
| 卷号 | 6期号:2页码:326-332 |
| 英文摘要 | A new solid polymer electrolyte composed of a polyimide matrix, an ionic liquid additive (1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, [Bmim][TFSI]), and a lithium salt (lithium bis(trifluoromethanesulfonyl)imide, LiTFSI) is fabricated by the solution-casting technique. The obtained self-standing polyimide (PI)-based polymer electrolyte (PI-100% BmimTFSI-60% LiTFSI) membranes show a great flexibility, transparency, and infiltration ability. As a result of the high thermal stability of the polyimide matrix, the thermal decomposition temperature of the electrolyte is high (420 degrees C). The ionic conductivity can be up to 1.73 x 10(-5) S cm(-1) at room temperature and reaches 1.26 x 10(-3) S cm(-1) at 80 degrees C. In addition, the PI-100% BmimTFSI-60% LiTFSI electrolytes have a wide electrochemical stability window of 4.8 V, a general lithium ion transference number of 0.12, and good interfacial stability and compatibility. In particular, the assembled LiFePO4/Li half cells made from this polyimide-based electrolyte can light up a light-emitting diode lamp at room temperature. |
| WOS记录号 | WOS:000424795100017 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38808]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Wang, Ailian,Xu, Hao,Liu, Fulin,et al. Polyimide-Based Self-Standing Polymer Electrolyte Membrane for Lithium-Ion Batteries[J]. ENERGY TECHNOLOGY,2018,6(2):326-332. |
| APA | Wang, Ailian.,Xu, Hao.,Liu, Fulin.,Liu, Xu.,Wang, Shi.,...&Zhang, Liaoyun.(2018).Polyimide-Based Self-Standing Polymer Electrolyte Membrane for Lithium-Ion Batteries.ENERGY TECHNOLOGY,6(2),326-332. |
| MLA | Wang, Ailian,et al."Polyimide-Based Self-Standing Polymer Electrolyte Membrane for Lithium-Ion Batteries".ENERGY TECHNOLOGY 6.2(2018):326-332. |
入库方式： OAI收割
来源：化学研究所
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