Bimetal-organic frameworks for functionality optimization: MnFe-MOF-74 as a stable and efficient catalyst for the epoxidation of alkenes with H2O2
文献类型：期刊论文
| 作者 | Yuan, Kuo; Song, Tianqun; Wang, Dawei; Zou, Ye; Li, Jinfeng; Zhang, Xiaotao; Tang, Zhiyong; Hu, Wenping |
| 刊名 | NANOSCALE
 |
| 出版日期 | JAN 28 2018 |
| 卷号 | 10期号:4页码:1591-1597 |
| 英文摘要 | In this work, we synthesized a series of microcrystalline MnxN100-x-MOF-74 (N = Fe, Co and Ni) materials by a one-pot reaction. Powder X-ray diffraction (PXRD) patterns of MnxN100-x-MOF-74 matched well with those of single-metal MOF-74, and the scanning electron microscopy (SEM) images exhibited homogeneous nanocrystallites aggregated together. The amounts and dispersion of metals were analyzed by using inductively coupled plasma (ICP) and energy-dispersive X-ray spectroscopy (EDS), separately. MnxN100-x-MOF-74 could remain crystalline and efficiently catalyze the epoxidation of alkenes in DMF with NaHCO3 and 30% H2O2. In particular, Mn29.39Fe70.61-MOF-74 can achieve almost 100% conversion for styrene with 95.0% selectivity towards styrene oxide and be reused at least five times without loss of activity. |
| WOS记录号 | WOS:000423355300004 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38819]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Yuan, Kuo,Song, Tianqun,Wang, Dawei,et al. Bimetal-organic frameworks for functionality optimization: MnFe-MOF-74 as a stable and efficient catalyst for the epoxidation of alkenes with H2O2[J]. NANOSCALE,JAN ,10(4):1591-1597. |
| APA | Yuan, Kuo.,Song, Tianqun.,Wang, Dawei.,Zou, Ye.,Li, Jinfeng.,...&Hu, Wenping.(JAN ).Bimetal-organic frameworks for functionality optimization: MnFe-MOF-74 as a stable and efficient catalyst for the epoxidation of alkenes with H2O2.NANOSCALE,10(4),1591-1597. |
| MLA | Yuan, Kuo,et al."Bimetal-organic frameworks for functionality optimization: MnFe-MOF-74 as a stable and efficient catalyst for the epoxidation of alkenes with H2O2".NANOSCALE 10.4(JAN ):1591-1597. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。