Spray-Drying-Induced Assembly of Skeleton-Structured SnO2/Graphene Composite Spheres as Superior Anode Materials for High Performance Lithium-Ion Batteries
文献类型：期刊论文
| 作者 | Liu, Dongdong; Kong, Zhen; Liu, Xuehua; Fu, Aiping; Wang, Yiqian; Guo, Yu-Guo; Guo, Peizhi; Li, Hongliang; Zhao, Xiu Song |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | JAN 24 2018 |
| 卷号 | 10期号:3页码:2515-2525 |
| 英文摘要 | Three-dimensional skeleton-structured assemblies of graphene sheets decorated with SnO2 nanocrystals are fabricated via a facile and large-scalable spray-drying-induced assembly process with commercial graphene oxide and SnO2 sol as precursors. The influences of different parameters on the morphology, composition, structure, and electrochemical performances of the skeleton-structured SnO2/graphene composite spheres are studied by XRD, TGA, SEM, TEM, Raman spectroscopy, and N-2 adsorption-desorption techniques. Electrochemical properties of the composite spheres as the anode electrode for lithium-ion batteries are evaluated. After 120 cycles under a current density of 100 mA g(-1), the skeleton-structured SnO2/graphene spheres still display a specific discharge capacity of 1140 mAh g(-1). It is roughly 9.5 times larger than that of bare SnO2 clusters. It could still retain a stable specific capacity of 775 mAh g(-1) after 50 cycles under a high current density of 2000 mA g(-1), exhibiting extraordinary rate ability. The superconductivity of the graphene skeleton provides the pathway for electron transportation. The large pore volume deduced from the skeleton structure of the SnO2/graphene composite spheres increases the penetration of electrolyte and the diffusion of lithium ions and also significantly enhances the structural integrity by acting as a mechanical buffer. |
| WOS记录号 | WOS:000423496500039 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38829]  |
| 专题 | 化学研究所_其它 |
| 推荐引用方式 GB/T 7714 | Liu, Dongdong,Kong, Zhen,Liu, Xuehua,et al. Spray-Drying-Induced Assembly of Skeleton-Structured SnO2/Graphene Composite Spheres as Superior Anode Materials for High Performance Lithium-Ion Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,JAN ,10(3):2515-2525. |
| APA | Liu, Dongdong.,Kong, Zhen.,Liu, Xuehua.,Fu, Aiping.,Wang, Yiqian.,...&Zhao, Xiu Song.(JAN ).Spray-Drying-Induced Assembly of Skeleton-Structured SnO2/Graphene Composite Spheres as Superior Anode Materials for High Performance Lithium-Ion Batteries.ACS APPLIED MATERIALS & INTERFACES,10(3),2515-2525. |
| MLA | Liu, Dongdong,et al."Spray-Drying-Induced Assembly of Skeleton-Structured SnO2/Graphene Composite Spheres as Superior Anode Materials for High Performance Lithium-Ion Batteries".ACS APPLIED MATERIALS & INTERFACES 10.3(JAN ):2515-2525. |
入库方式： OAI收割
来源：化学研究所
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