Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template
文献类型：期刊论文
| 作者 | Kang, Xinchen1,2; Sun, Xiaofu1,2; Ma, Xiaoxue1; Zhang, Pei1; Zhang, Zhanrong1; Meng, Qinglei1; Han, Buxing1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-10-02 |
| 卷号 | 59期号:41页码:12683-12686 |
| 关键词 | Heterogeneous Catalysis Hierarchical Porous Metals Ionic Liquids Material Synthesis Ternary System |
| 英文摘要 | It was found that nanodomains existed in the ionic liquid (IL)-based ternary system containing IL 1-ethyl-3-methylimidazole tetrafluoroborate (EmimBF4), IL 1-decyl-3-methylimidazole nitrate (DmimNO(3)) and water, and the size distribution of the domains varied continuously with the composition of the solution. A strategy to synthesize hierarchical porous metals using IL-based media as solvent and template is proposed, and the hierarchical porous Ru and Pt metals were prepared by the assembly of metal clusters of about 1.5 nm using this new method. It is demonstrated that the metals have micropores and mesopores, and the size distribution is tuned by controlling the composition of the solution. Porous Ru was used for a series of hydrogenation reactions. It has an outstanding catalytic performance owing to its special morphology and structure. |
| 语种 | 英语 |
| WOS记录号 | WOS:000423699300002 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38871]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Colloid & Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Xinchen,Sun, Xiaofu,Ma, Xiaoxue,et al. Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,59(41):12683-12686. |
| APA | Kang, Xinchen.,Sun, Xiaofu.,Ma, Xiaoxue.,Zhang, Pei.,Zhang, Zhanrong.,...&Han, Buxing.(2017).Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,59(41),12683-12686. |
| MLA | Kang, Xinchen,et al."Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59.41(2017):12683-12686. |
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来源：化学研究所
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